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3,5-BIS-(ALLYLOXY)-4-BROMOBENZALDEHYDE is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 355121-52-7 Structure
  • Basic information

    1. Product Name: 3,5-BIS-(ALLYLOXY)-4-BROMOBENZALDEHYDE
    2. Synonyms: 3,5-BIS-(ALLYLOXY)-4-BROMOBENZALDEHYDE
    3. CAS NO:355121-52-7
    4. Molecular Formula: C13H13BrO3
    5. Molecular Weight: 297.14452
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 355121-52-7.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: /
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 3,5-BIS-(ALLYLOXY)-4-BROMOBENZALDEHYDE(CAS DataBase Reference)
    10. NIST Chemistry Reference: 3,5-BIS-(ALLYLOXY)-4-BROMOBENZALDEHYDE(355121-52-7)
    11. EPA Substance Registry System: 3,5-BIS-(ALLYLOXY)-4-BROMOBENZALDEHYDE(355121-52-7)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 355121-52-7(Hazardous Substances Data)

355121-52-7 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 355121-52-7 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 3,5,5,1,2 and 1 respectively; the second part has 2 digits, 5 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 355121-52:
(8*3)+(7*5)+(6*5)+(5*1)+(4*2)+(3*1)+(2*5)+(1*2)=117
117 % 10 = 7
So 355121-52-7 is a valid CAS Registry Number.

355121-52-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name 4-bromo-3,5-bis(prop-2-enoxy)benzaldehyde

1.2 Other means of identification

Product number -
Other names 3,5-bis-allyloxy-4-bromo-benzaldehyde

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:355121-52-7 SDS

355121-52-7Relevant articles and documents

Large scale synthesis of the Cdc42 inhibitor secramine A and its inhibition of cell spreading

Xu, Bo,Pelish, Henry,Kirchhausen, Tomas,Hammond, Gerald B.

, p. 4149 - 4157 (2008/09/19)

We describe a large scale synthesis of secramine A. Consistent with its ability to inhibit activation of the small GTPase Cdc42, we find that secramine A inhibits cell spreading, a process previously shown to be Cdc42-dependent. The Royal Society of Chemistry 2006.

Experimental and theoretical studies on the thermal decomposition of heterocyclic nitrosimines

Bartsch,Yeh Moon Chae,Ham,Birney

, p. 7479 - 7486 (2007/10/03)

A series of substituted 2-nitrosiminobenzothiazolines (2) were synthesized by the nitrosation of the corresponding 2-iminobenzothiazolines (6). Thermal decomposition of 2a-f and of the seleno analogue 7 in methanol and of 3-methyl-2-nitrosobenzothiazoline (2a) in acetonitrile, 1,4-dioxane, and cyclohexane followed first-order kinetics. The activation parameters for thermal deazetization of 2a were measured in cyclohexane (ΔH? = 25.3 ± 0.5 kcal/mol, ΔS? = 1.3 ± 1.5 eu) and in methanol (ΔH? = 22.5 ± 0.7 kcal/mol, ΔS? = -12.9 ± 2.1 eu). These results indicate a unimolecular decomposition and are consistent with a proposed stepwise mechanism involving cyclization of the nitrosimine followed by loss of N2. The ground-state conformations of the parent nitrosiminothiazoline (9a) and transition states for rotation around the exocyclic C=N bond, electrocyclic ring closure, and loss of N2 were calculated using ab initio molecular orbital theory at the MP2/6-31G* level. The calculated gas-phase barrier height for the loss of N2 from 9a (25.2 kcal/mol, MP4(SDQ, FC)/6-31G*//MP2/6-31G* + ZPE) compares favorably with the experimental barrier for 2a of 25.3 kcal/mol in cyclohexane. The potential energy surface is unusual; the rotational transition state 9a-rot-ts connects directly to the orthogonal transition state for ring-closure 9aTS. The decoupling of rotational and pseudopericyclic bond-forming transition states is contrasted with the single pericyclic transition state (15TS) for the electrocyclic ring-opening of oxetene (15) to acrolein (16). For comparison, the calculated homolytic strength of the N-NO bond is 40.0 kcal/mol (MP4(SDQ, FC)/6-31G* + ZPE).

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