Bis(methoxycarbonyl)carbene Insertion into N-H Bonds: A Facile Route to N-Substituted Aminomalonic Esters
Bis(methoxycarbonyl)carbene, generated by the cooper(II)-catalyzed fragmentation of 2,5-dichlorothiophenium-1-bis(methoxycarbonyl)methylide (3) undergoes rapid and efficient insertion into the N-H bonds of primary and secondary amines to generate N-substi
Husinec, Suren,Juranic, Ivan,Llobera, Antonia,Porter, Alexander E. A.
p. 721 - 723
(2007/10/02)
ARYLIMINOMALONIC ESTERS
The condensation of nitrosobenzene with malonis esters is the best method for the production of dialkyl phenyliminomalonates, whereas the thermolysis of symmetrical and unsymmetrical di(arylamino)malonic esters is a good method for the synthesis of substituted dialkyl aryliminomalonates.
Markov, V. I.,Prosyanik, A. V.,Fedoseenko, D. V.,Loban', S. V.,Starovoitov, V. V.
p. 2209 - 2215
(2007/10/02)
More Articles about upstream products of 35757-92-7