Convergent total syntheses of fluvibactin and vibriobactin using molybdenum(vi) oxide-catalyzed dehydrative cyclization as a key step
Efficient total syntheses of fluvibactin and vibriobactin have been achieved via molybdenum(vi) oxide-catalyzed dehydrative cyclization, Sb(OEt)3-catalyzed ester-amide transformation, and WSCI and HOAt-promoted dehydrative amide formation. The Royal Society of Chemistry.
Sakakura, Akira,Umemura, Shuhei,Ishihara, Kazuaki
supporting information; experimental part
p. 3561 - 3563
(2009/02/05)
Significance of asymmetric sites in choosing siderophores as deferration agents
The syntheses of the microbial iron chelators L-fluviabactin, its unnatural enantiomer, D-fluviabactin, L-homofluviabactin, and L-agrobactin, are described. The key steps involve the selective bis-acylation of the terminal nitrogens of norspermidine, sper
Bergeron,Mei Gou Xin,Weimar,Smith,Wiegand
p. 2469 - 2478
(2007/10/03)
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