- DIRECT EPOXIDATION OF POLYCYCLIC AROMATIC COMPOUNDS BY SUPEROXIDE IN THE PRESENCE OF PHOSGENE DIMER
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Olefins and polycyclic aromatic compounds were oxidized to their epoxides by superoxide (O2-.) in the presence of phosgene dimer.The reaction mechanisms are discussed.
- Nagano, Tetsuo,Yokoohji, Kiyomi,Hirobe, Masaaki
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p. 3481 - 3484
(2007/10/02)
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- ABSOLUTE CONFIGURATION OF THE K-REGION 4,5-DIHYDRODIOLS AND 4,5-OXIDE OF BENZOPYRENE
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Application of the exciton chirality rule has allowed assignment of absolute configuration to (+)-trans-(4R,5R)-dihydroxy-4,5-dihydrobenzopyrene, a mammalian metabolite of the hydrocarbon.The cis 4,5-dihydrodiol and 4,5-oxide are also assigned based on correlation with the trans dihydrodiol.
- Kedzierski, B.,Thakker, D. R.,Armstrong, R. N.,Jerina, D. M.
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p. 405 - 408
(2007/10/02)
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