cas 37661-08-8, BACAMPICILLIN HYDROCHLORIDE | Articles data ｜lookchem

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37661-08-8

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Preparation of 1'-ethoxycarbonyl-oxyethyl esters of penicillins
Process for the preparation of 1'-ethoxy carbonyloxy ethyl esters of penicillins, wherein a compound of the formula STR1 in which A is phenyl, phenoxy or 4-hydroxyphenyl, B is hydrogen, an amino group or a protected amino group and Z is hydrogen or a cation selected from the group of alkali metal, tri (lower alkyl ) ammonium and tetra (lower alkyl) ammonium, is reacted with 1-bromoethyl ethyl carbonate in an organic solvent and when B is a protected amino group the protecting group is split off to yield a primary amino group. There are also provided novel compounds of the formula STR2 in which Ph is phenyl and R is CH3 -- or C2 H5 --.
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(2008/06/13)

Stabilization of ampicillin analogs in aqueous solution. VI. Kinetic analysis of the stabilization mechanism of bacampicillin with benzaldehyde in aqueous solution
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Fujiwara,Kawashima
p. 1202 - 1213
(2007/10/02)

Studies on prodrugs. III. A convenient and practical preparation of ampicillin prodrugs
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Ikeda,Sakamoto,Kondo,et al.
p. 4316 - 4322
(2007/10/02)

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Chemical Properties

Melting Point: 171-176° (dec)
Boiling Point: 695.4°C at 760 mmHg
Flash Point:374.3°C
Solubility:Soluble in water, freely soluble in ethanol (96 per cent), soluble in methylene chloride.
Vapor Pressure: 1.39E-19mmHg at 25°C
PSA: 162.56000
LogP: 3.12690

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