cas 37858-03-0, 1H,1H,2H,2H-Tridecafluorooctyl acetate | Articles data ｜lookchem

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37858-03-0

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Investigations into the use of a polyfluorooctanol as an auxiliary component for an aldol reaction
Results are reported on the efficiency of polyfluorooctanol as a perfluorous auxiliary component in the aldol reaction between the enolate derived from polyfluorooctyl acetate and 2-fluorobenzaldehyde. Reduction of the corresponding polyfluoro β-hydroxy ester with Super Hydride gave the required 1,3-diol in good yield.
Eames, Jason,Khanom, Hasina
p. 266 - 277
(2007/10/03)

Synthesis of fluoroalkyl ethanal: R(F)CH2CHO
Aldehydes R(F)CH2CHO (R(F) is a linear perfluoroalkyl chain) have been obtained in the addition reaction of R(F)I to vinyl acetate in the presence of zinc. R(F)CH2CHIOAc is formed as an intermediate in the course of the reaction. Under appropriate conditions, R(F)CH2CHO and its acylal or acetal derivatives are obtained in good yields.
Laurent,Blancou,Commeyras
p. 2489 - 2492
(2007/10/02)

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Chemical Properties

Melting Point: -73 °C
Boiling Point: 172 °C
Flash Point:66 °C
Density: 1.5515 g/cm³
Refractive Index: 1.3215
PSA: 26.30000
LogP: 4.67840

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