3808-87-5

Basic information

• Product Name: BIS(2,4,5-TRICHLOROPHENYL) DISULFIDE
• Synonyms: 2,4,5-TRICHLOROPHENYL DISULFIDE;BIS(2,4,5-TRICHLOROPHENYL) DISULFIDE;BIS(2,4,5-TRICHLOROPHENYL) DISULPHIDE;DI(2,4,5-TRICHLOROPHENYL) DISULFIDE;2,2,4,4,5,5-Hexachlorophenyl disulphide~2,4,5-Trichlorophenyl disulphide;2,4,5-trichlorophenyl disulphide;2,4,5-TRICHLOROPHENYL DISULFIDE 98%;Bis(2,4,5-trichlorophenyl) persulfide
• CAS NO: 3808-87-5
• Molecular Formula: C₁₂H₄Cl₆S₂
• Molecular Weight: 425.01
• EINECS: 223-279-2
• Mol File: 3808-87-5.mol

Chemical Properties

• Melting Point: 140-144 °C(lit.)
• Boiling Point: 460.9°Cat760mmHg
• Flash Point: 213.2°C
• Appearance: /
• Density: 1.6505 (estimate)
• Vapor Pressure: 3.08E-08mmHg at 25°C
• Refractive Index: 1.718
• CAS DataBase Reference: BIS(2,4,5-TRICHLOROPHENYL) DISULFIDE(CAS DataBase Reference)
• NIST Chemistry Reference: BIS(2,4,5-TRICHLOROPHENYL) DISULFIDE(3808-87-5)
• EPA Substance Registry System: BIS(2,4,5-TRICHLOROPHENYL) DISULFIDE(3808-87-5)

Safety Data

• Safety Statements: S24/25:Avoid contact with skin and eyes.
• WGK Germany: 3
• Hazardous Substances Data: 3808-87-5(Hazardous Substances Data)

Usage

Uses

Used in Pesticide Industry:
Bis(2,4,5-trichlorophenyl) disulfide is used as a pesticide for its strong antimicrobial and antifungal properties, helping to protect crops from various pests and diseases.
Used in Fungicide Industry:
In the fungicide industry, Bis(2,4,5-trichlorophenyl) disulfide serves as an effective antifungal agent, preventing the growth of fungi that can cause damage to plants and reduce crop yields.
However, it is important to note that Bis(2,4,5-trichlorophenyl) disulfide is classified as a persistent organic pollutant and has been shown to have toxic effects on aquatic organisms. Its potential to bioaccumulate and harm the environment has led to international regulations and restrictions on its use and production. Understanding the structure and properties of this chemical is crucial for assessing its potential impact on human health and the environment.

InChI:InChI=1/C12H4Cl6S2/c13-5-1-9(17)11(3-7(5)15)19-20-12-4-8(16)6(14)2-10(12)18/h1-4H

Upstream product

• 15945-07-0 2,4,5-trichlorobenzensulfonyl chloride 
• 24082-44-8 bis-(2,4,5-trichloro-phenyl)-trisulfide 
• 636-30-6 2,4,5-trichloroaniline 
• 88-67-5 2-Iodobenzoic acid 
• 3773-14-6 2,4,5-trichlorothiophenol 
• 10439-21-1 2,4,5-trichloro-benzenesulfinic acid 
• 62726-90-3 2,4,5-trichlorobenzenesulfenyl chloride 
• 594-27-4 tetramethylstannane 
• 120-82-1 1,2,4-Trichlorobenzene 

Downstream Products

• 102105-06-6 N-(diphenylmethylene)-2,4,5-trichlorophenylsulfenamide 
• 102105-04-4 N-(dibenzocyclohepten-5-ylidene)-2,4,5-trichlorophenylsulfenamide 
• 3773-14-6 2,4,5-trichlorothiophenol 
• 62726-90-3 2,4,5-trichlorobenzenesulfenyl chloride 
• 247237-66-7 4-hydroxy-1-phenyl-3-(2,4,5-trichlorophenylthio)-2(1H)-quinolone 
• 247237-75-8 4-hydroxy-1-phenyl-3-(2,4,5-trichlorophenylthio)-5,6,7,8-tetrahydro-2(1H)-quinolone 
• 247237-97-4 4-hydroxy-3-(2,4,5-trichlorophenylsulfonyl)-1-phenyl-5,6,7,8-tetrahydro-2(1H)-quinolone 
• 264926-02-5 [2,4,5-Cl₃(C₆H₂)SSnMe₃] 
• 15945-07-0 2,4,5-trichlorobenzensulfonyl chloride 
• 1429474-47-4 4-methyl-3-((2,4,5-trichlorophenyl)thio)-1H-indole-2-carboxylic acid 
• 1429474-45-2 6-methyl-3-((2,4,5-trichlorophenyl)thio)-1H-indole-2-carboxylic acid 
• 1429474-46-3 7-methyl-3-((2,4,5-trichlorophenyl)thio)-1H-indole-2-carboxylic acid 
• 96463-46-6 1,1’-(methylenedisulfanediyl)bis(2,4,5-trichlorobenzene) 

Relevant articles and documents

A novel oxidizing reagent based on potassium ferrate(VI)

A new, efficient preparation has been devised for potassium ferrate(VI) (K2FeO4). The ability of this high-valent iron salt for oxidizing organic substrates in nonaqueous media was studied. Using benzyl alcohol as a model, the catalytic activity of a wide range of microporous adsorbents was ascertained. Among numerous solid supports of the aluminosilicate type, the K10 montmorillonite clay was found to be best at achieving quantitative formation of benzaldehyde, without any overoxidation to benzoic acid. The roles of the various parameters (reaction time and temperature, nature of the solvent, method of preparation of the solid reagent) were investigated. The evidence points to a polar reaction mechanism. The ensuing procedure was applied successfully, at room temperature, to oxidation of a series of alcohols to aldehydes and ketones, to oxidative coupling of thiols to disulfides, and to oxidation of nitrogen derivatives. At 75°C, the reagent has the capability of oxidizing both activated and nonactivated hydrocarbons. Toluene is turned into benzyl alcohol (and benzaldehyde). Cycloalkanes are also oxidized, in significant (30-40%) yields, to the respective cycloalkanols (and cycloalkanones). Thus, potassium ferrate, used in conjunction with an appropriate heterogeneous catalyst, is a strong and environmentally friendly oxidant.

CLAY-SUPPORTED REAGENTS IV. A NOVEL COUPLING OF THIOLS INTO DISULPHIDES, VIA THIONITRITE INTERMEDIATES USING A CLAY-SUPPORTED NITROSATION REAGENT.

Thiols are converted into symmetrical disulphides, under very mild conditions, by bentonite-supported Fe(NO3)3*H2O.

REACTION OF N,N'-THIONYLDIIMIDAZOLE WITH THIOLS: A SULFUR TRANSFER REACTION

Reaction of N,N'-thionyldiimidazole with thiols effects the formation of disulfides and trisulfides.These results are rationalized by assuming that the thiols react with N,N'-thionyldiimidazole to produce the disulfides and N,N'-thiobisimidazole which subsequently reacts with the starting thiols to give the trisulfides.