38091-78-0

Basic information

• Product Name: ethyl 2-cyano-3-methyl-nonanoate
• Synonyms: 2-Cyano-3-methylnonanoicacid ethyl ester; NSC 408292
• CAS NO: 38091-78-0
• Molecular Formula: C13H23NO2
• Molecular Weight: 0
• Mol File: 38091-78-0.mol

Chemical Properties

• Boiling Point: 256.7°C at 760 mmHg
• Flash Point: 114.1°C
• Appearance: /
• Density: 0.935g/cm³
• Vapor Pressure: 0.0152mmHg at 25°C
• Refractive Index: 1.443
• CAS DataBase Reference: ethyl 2-cyano-3-methyl-nonanoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 2-cyano-3-methyl-nonanoate(38091-78-0)
• EPA Substance Registry System: ethyl 2-cyano-3-methyl-nonanoate(38091-78-0)

Safety Data

• Hazardous Substances Data: 38091-78-0(Hazardous Substances Data)

Usage

InChI:InChI=1/C13H23NO2/c1-4-6-7-8-9-11(3)12(10-14)13(15)16-5-2/h11-12H,4-9H2,1-3H3

Upstream product

• 16630-91-4 2-methylheptanal 
• 631-61-8 ammonium acetate 
• 105-56-6 ethyl 2-cyanoacetate 
• 557-35-7 2-bromooctane 
• 111-67-1 2-octene 
• 5978-70-1 (R)-Octan-2-ol 
• 62820-85-3 (S)-2-<(Methanesulfonyl)oxy>octane 

Relevant articles and documents

CARBON-CARBON BOND FORMATION USING MANGANESE(III) ACETATE AS AN ELECTROCHEMICAL MEDIATOR

Anodic oxidation in a solution containing a variety of olefins and a small amount of Mn(OAc)2*4H2O brought about Mn+3-mediated carbon-carbon bond formation, such as efficient carboxymethylation of styrene derivatives to the corresponding γ-aryl-γ-butyrolactones, and selective coupling of active methylene compounds with non-activated monoolefins, unconjugated dienes or 5-arylpent-1-enes.

Selective Coupling of Non-Activated Olefins with Ethyl Cyanoacetate by Mn(3+)-Mediated Anodic Oxidation

Novel carbon-carbon bond formation of non-activated olefins with ethyl cyanoacetate has been developed by anodic oxidation using only small amount of Mn(OAc)2*4H2O to give selectively either saturated or unsaturated coupling products depending upon the pr