- Synthetic applications and spectroscopic investigations of the (NSCl)3-SO2Cl2 system
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Solutions of (NSCl)3 in the presence of excess SO2Cl2 behave as a source of the synthetic equivalent "NSCl3" in reactions with methacrylonitrile or thioacetamide to give 4-cyanoisothiazole (78percent) or 5-methyl-1,3,2,4-dithiadiazolium chloride (63percen
- Apblett, Allen,Chivers, Tristram
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p. 650 - 654
(2007/10/02)
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- The in situ Generation of Thiazyl Trichloride: A Synthon for C-N-S Heterocycles
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The novel reagent NSCl3 is readily generated by treatment of (NSCl)3 with an excess of SO2Cl2; the reactions of NSCl3 with methacrylonitrile or thioacetamide produce 4-cyanoisothiazole or 5-methyl-1,3,2,4-dithiazolium chloride, respectively, in good yields.
- Apblett, Allen,Chivers, Tristram
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p. 1889 - 1890
(2007/10/02)
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