Free Radicals in Organic Synthesis. A Novel Synthesis of Ethylene Glycol Based on Formaldehyde
1,3-Dioxolane reacted with formaldehyde in the presence of free radical initiators to produce 2-(hydroxymethyl)-1,3-dioxolane in moderate yield. 2-(Hydroxymethyl)-1,3-dioxolane was catalytically hydrogenated to ethylene glycol.
Sanderson, John R.,Yeakey, Ernest L.,Lin, Jiang J.,Duranleau, Roger,Marquis, Edward T.
p. 3243 - 3246
(2007/10/02)
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