401584-82-5

Basic information

• Product Name: Benzene, 1-(cyclopropylmethyl)-4-(1-methylethyl)- (9CI)
• Synonyms: Benzene, 1-(cyclopropylmethyl)-4-(1-methylethyl)- (9CI)
• CAS NO: 401584-82-5
• Molecular Formula: C₁₃H₁₈
• Molecular Weight: 174.28202
• Product Categories: ISOPROPYL
• Mol File: 401584-82-5.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Benzene, 1-(cyclopropylmethyl)-4-(1-methylethyl)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(cyclopropylmethyl)-4-(1-methylethyl)- (9CI)(401584-82-5)
• EPA Substance Registry System: Benzene, 1-(cyclopropylmethyl)-4-(1-methylethyl)- (9CI)(401584-82-5)

Safety Data

• Hazardous Substances Data: 401584-82-5(Hazardous Substances Data)

Upstream product

• 1065010-87-8 potassium cyclopropyltrifluoroborate 
• 2051-18-5 4-isopropylbenzyl chloride 

Downstream Products

• 1817-47-6 4-nitrocumene 
• 120383-85-9 1-(cyclopropylmethyl)-4-nitrobenzene 

Relevant articles and documents

Suzuki coupling of potassium cyclopropyl- and alkoxymethyltrifluoroborates with benzyl chlorides

Efficient Csp3-Csp3 Suzuki couplings have been developed with both potassium cyclopropyl- and alkoxymethyltrifluoroborates. Moderate to good yields have been achieved in the cross-coupling of potassium cyclopropyltrifluoroborate with benzyl chlorides possessing electron-donating or electron-withdrawing substituents. Benzyl chloride was also successfully cross-coupled to potassium alkoxymethyltrifluoroborates derived from primary, secondary, and tertiary alcohols.

Transformations of para-substituted benzylcyclopropanes, allylbenzenes, and diphenylmethanes under nitration with nitric acid in acetic anhydride

Electrophilic nitration of benzylcyclopropanes, allylbenzenes, and diphenylmethanes containing ortho, para-orienting substituents in the para position of the benzene ring results mainly in replacement of the cyclopropylmethyl, allyl, or benzyl group, respectively (ipso substitution). The nitration of 4-cyclopropylallylbenzene is not accompanied by nitrodealkylation, and the products are only 2- and 3-nitro-4-cyclopropylallylbenzenes.