2051-18-5Relevant articles and documents
Synthesis of chlorinated alkylbibenzyls and 9-chlororetene
Nevalainen, T.
, p. 847 - 854 (1995)
The synthesis of chlorinated alkylbibenzyls and 9-chlororetene is described. These compounds were synthesized for use as model compounds in analytical and toxicological characterization. The structures of the synthesized model compounds found to be very similar to those indentified in pulp mill effluent and products. The (1)H NMR and mass spectral data for the compounds are also reported.
Triazole derivative as well as preparation method and application thereof
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Paragraph 0053-0055; 0065-0066; 0068, (2020/06/09)
The invention relates to a triazole derivative as well as a preparation method and application thereof, which belong to the technical field of organic synthetic drugs. The structure of the triazole derivative is shown as a formula I. In the formula I, R1 and R2 are H, Cl, Br,-CF3,-CH(CH3)2 or -OCH3, and R1 and R2 are not H at the same time. R3 is -CH2 or -COCH2; X and Y are N or C, X and Y are not C at the same time, and X and Y are not N at the same time. The triazole derivative disclosed by the invention has a certain inhibition effect on germs of various crop diseases. Small toxic andside effects on plants are achieved. The preparation method of the triazole derivative is simple.
A practical and convenient Blanc-type chloromethylation catalyzed by zinc chloride under solvent-free conditions
Tang, Jian,Liu, Hongtao,He, Kailun,Zhang, Xingxian
, p. 925 - 932 (2019/03/17)
Chloromethylation of various aromatic hydrocarbons and substituted phenolic derivatives with dimethoxymethane and chlorosulfonic acid was carried out in the presence of 10 mol% of ZnCl2 in a mild and efficient manner under solvent-free conditions. In addition, 2,6-dimethyltyrosine was synthesized in high yield via this protocol.