Ambident Electrophilic Character of Thioxophosphoranesulphenyl Bromides =P(S)SBr. A Novel Observation of Electrophilic Addition to a Carbon-Carbon Double Bond
The thioxophosphoranesulphenyl bromides (1) act as ambident electrophiles towards alkenes and react, depending on the structure of the alkene, to give either the normal addition products -SC(R1)(R2)CR3(R4)(Br) or 1,2-dibromides and -disulphides.
Lopusinski, Andrzej,Michalski, Jan,Potrzebowski, Mark
p. 1362 - 1364
(2007/10/02)
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