4170-50-7Relevant articles and documents
Ambident Electrophilic Character of Thioxophosphoranesulphenyl Bromides =P(S)SBr. A Novel Observation of Electrophilic Addition to a Carbon-Carbon Double Bond
Lopusinski, Andrzej,Michalski, Jan,Potrzebowski, Mark
, p. 1362 - 1364 (2007/10/02)
The thioxophosphoranesulphenyl bromides (1) act as ambident electrophiles towards alkenes and react, depending on the structure of the alkene, to give either the normal addition products -SC(R1)(R2)CR3(R4)(Br) or 1,2-dibromides and -disulphides.