459432-60-1Relevant articles and documents
Rhodium- and iridium-catalyzed allylation of electron-rich arenes with allyl tosylate
Tsukada, Naofumi,Yagura, Yasushige,Sato, Tetsuo,Inoue, Yoshio
, p. 1431 - 1434 (2007/10/03)
The allylation of electron-rich arenes with allyl tosylate proceeded at 0°C in the presence of [Rh(nbd)(CH3CN)2]PF 6. Various oxygenated arenes were allylated with high para-selectivity in almost all cases. Especially in t
Reagent Design and Study of Allene as a Promising Class of Reagents (Synthons) for Cycloaddition. The Site Selective and Regioselective Diels-Alder Reactions of (Phenylsulfonyl)propadiene and Alkylation of the Adducts.
Hayakawa, Kenji,Nishiyama, Hitoshi,Kanematsu, Ken
, p. 512 - 517 (2007/10/02)
The cycloaddtion reaction of title compound 1 with 1,3-dienes and troponoid compounds has been investigated.The reactions with dienes 2-8 proceeded in remarkable site selective and regioselective manners to give the Diels-Alder adducts 9-15 possessing an