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107-05-1

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Product FOB Price Min.Order Supply Ability Supplier
Allyl chloride
Cas No: 107-05-1
No Data 25 Kilogram 20 Metric Ton/Day QINGDAO ON-BILLION INDUSTRAIL CO.,LTD Contact Supplier
3-chloropropene; allyl chloride
Cas No: 107-05-1
No Data 100 Kilogram 30 Metric Ton/Day Zouping Sanhao Chemical Co., Ltd . Contact Supplier
Amadis Chemical offer CAS#107-05-1;CAT#A801564
Cas No: 107-05-1
No Data 10 Milligram Amadis Chemical Co., Ltd. Contact Supplier
1-Propene, 3-chloro- 107-05-1
Cas No: 107-05-1
No Data No Data No Data Hunan Russell Chemicals Technology Co.,Ltd Contact Supplier
High quality Allyl chloride supplier in China CAS NO.107-05-1
Cas No: 107-05-1
USD $ 1750.0-1900.0 / Kilogram 1 Kilogram 20 Metric Ton/Day Shandong Jiading Chemical Co.,ltd Contact Supplier
1-Propene, 3-chloro-
Cas No: 107-05-1
USD $ 500.0-500.0 / Gram 1 Gram 1000 Gram/Day Pure Chemistry Scientific Inc. Contact Supplier

107-05-1 Usage

Health Hazard

Causes marked irritation of skin and may burn. Burns the eyes; effect may be delayed.

Fire Hazard

Special Hazards of Combustion Products: Releases irritating hydrogen chloride gas on combustion

General Description

A clear colorless liquid with an unpleasant pungent odor. Flash point -20°F. Boiling point 113°F. Less dense than water (7.8 lb / gal) and insoluble in water. Hence floats on water. Vapor irritates skin, eyes and mucous membranes. Vapors are heavier than air. Long exposure to low concentrations or short exposure to high concentrations may have adverse health effects from inhalation or skin absorption.

Uses

In the synthesis of allyl Compounds.

Chemical Properties

colourless, light yellow or amber liquid with an unpleasant smell

Purification Methods

Likely impurities include 2-chloropropene, propyl chloride, iso-propyl chloride, 3,3-dichloropropane, 1,2-dichloropropane and 1,3-dichloropropane. Purify it by washing with conc HCl, then with Na2CO3 solution, dry it with CaCl2, and distil it through an efficient column [Oae & Vanderwerf J Am Chem Soc 75 2724 1953]. [Beilstein 1 IV 738.] LACHRYMATORY, TOXIC.

Reactivity Profile

Allyl chloride presents a serious fire and explosion hazard when exposed to heat, flame or oxidizing agents. Polymerizes violently and exothermically with Lewis acids (aluminum chloride, boron trifluoride, sulfuric acid) or metals (aluminum, magnesium, zinc, or galvanized metal) [MCA SD-99, 1973]. Incompatible with acids (nitric acid, chlorosulfonic acid, oleum), with strong bases (sodium hydroxide, potassium hydroxide), with ethyleneimine and ethylenediamine [Lewis, 3rd ed., 1993, p. 36]. Attempts to alkylate benzene or toluene using Allyl chloride in the presence of ethylaluminum chlorides have led to explosions.

Air & Water Reactions

Highly flammable. Insoluble in water.

107-05-1 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Supelco (442446)  3-Chloro-1-propene  analytical standard 107-05-1 000000000000442446 234.00CNY Detail
Alfa Aesar (A14330)  Allyl chloride, 98%, stab. with propylene oxide    107-05-1 500ml 433.0CNY Detail
Alfa Aesar (A14330)  Allyl chloride, 98%, stab. with propylene oxide    107-05-1 100ml 251.0CNY Detail
TCI America (C0274)  Allyl Chloride  >98.0%(GC) 107-05-1 500mL 255.00CNY Detail
TCI America (C0274)  Allyl Chloride  >98.0%(GC) 107-05-1 25mL 155.00CNY Detail

107-05-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name Allyl chloride

1.2 Other means of identification

Product number -
Other names 2-propenyl acetoacetate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Almost all of the allyl chloride produced is used to make epichlorohydrin and glycerin. Allyl chloride is also used in the synthesis of allyl compounds such as allyl alcohol, allyl amines, allyl esters, and polyesters. Allyl chloride derivatives are found in varnish, plastics, adhesives, perfumes, pharmaceuticals, and insecticides.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:107-05-1 SDS

107-05-1Synthetic route

2-propynyl chloride
624-65-7

2-propynyl chloride

3-chloroprop-1-ene
107-05-1

3-chloroprop-1-ene

Conditions
ConditionsYield
With piperazine; hydrogen In ethanol at 80℃; under 4500.45 Torr; for 24h;99%
With piperazine; hydrogen In ethanol at 100℃; under 4500.45 Torr; for 15h; Green chemistry;
With hydrogen In ethanol at 100℃; under 4500.45 Torr; for 24h; chemoselective reaction;87 %Chromat.
π-allyl(dichloro)(pentamethylcyclopentadienyl)ruthenium (IV)

π-allyl(dichloro)(pentamethylcyclopentadienyl)ruthenium (IV)

A

(η(5)-C5Me5)Ru(CO)2Cl

(η(5)-C5Me5)Ru(CO)2Cl

B

3-chloroprop-1-ene
107-05-1

3-chloroprop-1-ene

Conditions
ConditionsYield
With CO In decane (CO); heating (2 h, 140°C), cooling; chromy. (silica gel, ether);A 96%
B n/a
With CO In decane (CO); heating (2 h, 120°C), cooling; chromy. (silica gel, ether);A 16%
B n/a
N,N-dimethyl-2-propen-1-amine
2155-94-4

N,N-dimethyl-2-propen-1-amine

3-chloroprop-1-ene
107-05-1

3-chloroprop-1-ene

Conditions
ConditionsYield
With 2-chloro-4,6-dimethoxy-1 ,3,5-triazine In toluene Reflux;96%
Ru(η5-C5H5)(η3-C3H5)Cl2

Ru(η5-C5H5)(η3-C3H5)Cl2

A

(η(5)-cyclopentadienyl)dicarbonylchlororuthenium(II)

(η(5)-cyclopentadienyl)dicarbonylchlororuthenium(II)

B

3-chloroprop-1-ene
107-05-1

3-chloroprop-1-ene

Conditions
ConditionsYield
With CO In decane (CO); heating (2 h, 140°C), cooling; chromy. (silica gel, ether);A 93%
B n/a
propene
187737-37-7

propene

A

2-chloropropene
557-98-2

2-chloropropene

B

1,2-Dichloropropane
26198-63-0, 78-87-5

1,2-Dichloropropane

C

E/Z-1,3-Dichloropropene
542-75-6

E/Z-1,3-Dichloropropene

D

isopropyl chloride
75-29-6

isopropyl chloride

E

propenyl chloride
590-21-6

propenyl chloride

F

3-chloroprop-1-ene
107-05-1

3-chloroprop-1-ene

Conditions
ConditionsYield
With aluminum oxide; copper dichloride; dibenzoyl peroxide at 489.9℃; for 0.000555556h; Product distribution; Mechanism; also other temperatures (503 K - 753 K) and initiators (chloral dioxyperoxide);A 0.7%
B 3.3%
C 0.8%
D 1.8%
E 0.9%
F 91.4%
cis,trans-[Ir(Cl3)(-CH=CHPPh3)2(CO)(PPh3)2](ClO4)2

cis,trans-[Ir(Cl3)(-CH=CHPPh3)2(CO)(PPh3)2](ClO4)2

allyl bromide
106-95-6

allyl bromide

cis,cis-[IrBr2(CH3)(-CH=CHPPh3)2(CO)(PPh3)](ClO4)

cis,cis-[IrBr2(CH3)(-CH=CHPPh3)2(CO)(PPh3)](ClO4)

B

3-chloroprop-1-ene
107-05-1

3-chloroprop-1-ene

Conditions
ConditionsYield
In chloroform A mixt. of reagents in CHCl3 was stirred at 50°C for 2 days, cooled to room temp.;; elem. anal.;;A 91%
B n/a
Ru(η5-C5H5)(η3-C3H5)Cl2

Ru(η5-C5H5)(η3-C3H5)Cl2

para-xylene
106-42-3

para-xylene

A

(η5-C5H5)Ru(p-xylene)Cl

(η5-C5H5)Ru(p-xylene)Cl

B

3-chloroprop-1-ene
107-05-1

3-chloroprop-1-ene

Conditions
ConditionsYield
(N2); heating (17 h, 140°C), cooling; concn., chromy. (silica gel, MeOH);A 88%
B n/a
epichlorohydrin
106-89-8

epichlorohydrin

3-chloroprop-1-ene
107-05-1

3-chloroprop-1-ene

Conditions
ConditionsYield
With zirconium(IV) chloride; sodium iodide In acetonitrile for 0.0166667h; Heating;87%
With Silphos; iodine In N,N-dimethyl-formamide at 20℃; for 0.416667h;74%
With iodine; triphenylphosphine In N,N-dimethyl-formamide at 20℃;
With hydrogen; triethyl phosphite In isopropyl alcohol at 100℃; under 4500.45 Torr; for 12h; Glovebox; chemoselective reaction;85 %Chromat.
allyl phenyl ether
1746-13-0

allyl phenyl ether

A

3-chloroprop-1-ene
107-05-1

3-chloroprop-1-ene

B

phenol
108-95-2

phenol

Conditions
ConditionsYield
With bis(benzonitrile)palladium(II) dichloride In benzene for 20h; Product distribution; Heating; further subst.; use of deallylation as deprotection of phenolic hydroxyl groups;A n/a
B 86%
N-allyl-N-cyclohexylmethylamine
22416-98-4

N-allyl-N-cyclohexylmethylamine

2,2,2-Trichloroethyl chloroformate
17341-93-4

2,2,2-Trichloroethyl chloroformate

A

Cyclohexyl-methyl-carbamic acid 2,2,2-trichloro-ethyl ester
87876-79-7

Cyclohexyl-methyl-carbamic acid 2,2,2-trichloro-ethyl ester

B

3-chloroprop-1-ene
107-05-1

3-chloroprop-1-ene

Conditions
ConditionsYield
In benzene Heating;A 85%
B n/a
hexyl 2-propenyl ether
3295-94-1

hexyl 2-propenyl ether

phenylacetyl chloride
103-80-0

phenylacetyl chloride

A

Phenylessigsaeurehexylester
5421-17-0

Phenylessigsaeurehexylester

B

3-chloroprop-1-ene
107-05-1

3-chloroprop-1-ene

Conditions
ConditionsYield
With zinc In Petroleum ether at 28℃; for 2h;A 85%
B n/a
cyclopropane
75-19-4

cyclopropane

A

cyclopropyl chloride
7393-45-5

cyclopropyl chloride

B

1,1-dichlorocyclopropane
2088-35-9

1,1-dichlorocyclopropane

C

1,3-Dichloropropane
142-28-9

1,3-Dichloropropane

D

3-chloroprop-1-ene
107-05-1

3-chloroprop-1-ene

Conditions
ConditionsYield
With chlorine; silicon tetrafluoride at 600℃; Product distribution; Irradiation;A 83.5%
B 4%
C n/a
D 2.6%
allyl alcohol
107-18-6

allyl alcohol

3-chloroprop-1-ene
107-05-1

3-chloroprop-1-ene

Conditions
ConditionsYield
With benzoyl chloride; N,N-dimethyl-formamide at 0 - 20℃; for 5.5h;82%
With hydrogenchloride; sulfuric acid; copper(l) chloride75.4%
With priphenylchlorophosphonium phosphorodichloridate at 20℃; Arbuzov reaction;75%
allyl diphenyl phosphate
19206-69-0

allyl diphenyl phosphate

3-chloroprop-1-ene
107-05-1

3-chloroprop-1-ene

Conditions
ConditionsYield
With lithium chloride In N,N-dimethyl-formamide for 0.166667h; Ambient temperature;75%
N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

epichlorohydrin
106-89-8

epichlorohydrin

A

formic acid 1-bromomethyl-2-chloroethyl ester
101257-40-3

formic acid 1-bromomethyl-2-chloroethyl ester

B

3-chloroprop-1-ene
107-05-1

3-chloroprop-1-ene

Conditions
ConditionsYield
With bromine; triphenylphosphine at 0℃; for 1h;A 75%
B n/a

107-05-1Related news

Research paperUnderstanding the pathways of improved chlorohydrination of Allyl chloride (cas 107-05-1) with HCl and H2O2 catalyzed by titanium-incorporated zeolites08/20/2019

Chlorine based olefin chlorohydrination reaction is one of the most hazard and polluted processes for manufacturing epoxy compounds. To solve these drawbacks, we have exploited a totally novel allyl chloride chlorohydrination route, using HCl and H2O2 as raw materials, catalyzed by hollow titani...detailed

Experiments and kinetics of the epoxidation of Allyl chloride (cas 107-05-1) with H2O2 over organic base treated TS-1 catalysts08/19/2019

An efficacious approach to improve the catalytic performance of titanium silicalite-1 (TS-1) catalysts in epoxidation of allyl chloride with hydrogen peroxide has been developed. A series of modified TS-1 catalysts were prepared by corroding the classic TS-1 catalyst with different concentration...detailed

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