METHOD FOR THE PRODUCTION OF ORGANOSILICON COMPOUNDS COMPRISING CARBOXY RADICALS
The invention relates to a method for the production of organosilicon compounds (2) comprising carbonyl radicals by oxidation of organosilicion compounds (1) comprising carbinol radicals with the aid of a mediator (3) selected from a group of aliphatic, cycloaliphatic, heterocyclic and aromatic NO-, NOH- and (I)-containing compounds and an oxidizing agent (4) under the proviso that the reaction is carried out with constant control of the pH value at a pH = 3 and the carbonyl radicals in the organosilicon compounds (1) thus used are oxidized to form predominantly carboxy radicals.
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Page/Page column 29-30
(2008/06/13)
BREAKAGE OF Si-CH3 AND Si-R BONDS IN 3-(ALKYLDIMETHYLSILYL)PROPIONIC ACIDS UNDER THE ACTION OF CONCENTRATED SULFURIC ACID
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Smirnova, G. S.,Nikonov, B. A.,Andreev, D. N.
p. 2048 - 2050
(2007/10/02)
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