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477249-36-8

2H-Azirine, 3-(4-nitrophenyl)- is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 477249-36-8 Structure

  • Basic information

    1. Product Name: 2H-Azirine, 3-(4-nitrophenyl)-
    2. Synonyms: 2H-Azirine, 3-(4-nitrophenyl)-
    3. CAS NO:477249-36-8
    4. Molecular Formula: C8H6N2O2
    5. Molecular Weight: 162.15
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 477249-36-8.mol

  • Chemical Properties

    1. Melting Point: 103-104 °C
    2. Boiling Point: 295.4±42.0 °C(Predicted)
    3. Flash Point: N/A
    4. Appearance: /
    5. Density: 1.41±0.1 g/cm3(Predicted)
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. PKA: 3.36±0.20(Predicted)
    10. CAS DataBase Reference: 2H-Azirine, 3-(4-nitrophenyl)-(CAS DataBase Reference)
    11. NIST Chemistry Reference: 2H-Azirine, 3-(4-nitrophenyl)-(477249-36-8)
    12. EPA Substance Registry System: 2H-Azirine, 3-(4-nitrophenyl)-(477249-36-8)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 477249-36-8(Hazardous Substances Data)

477249-36-8 Usage

Chemical compound

2H-Azirine, 3-(4-nitrophenyl)-

Derivative of azirine

Contains a nitrogen atom in a three-membered heterocyclic organic compound

4-nitrophenyl group

Gives specific properties and reactivity to the compound

Uses

Organic synthesis and pharmaceutical research

Potential

Building block for the synthesis of biologically active compounds

Studied for

Potential use as a reactive intermediate in chemical reactions

Importance

Significant compound in the field of organic chemistry

Check Digit Verification of cas no

The CAS Registry Mumber 477249-36-8 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 4,7,7,2,4 and 9 respectively; the second part has 2 digits, 3 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 477249-36:
(8*4)+(7*7)+(6*7)+(5*2)+(4*4)+(3*9)+(2*3)+(1*6)=188
188 % 10 = 8
So 477249-36-8 is a valid CAS Registry Number.

477249-36-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name 3-(4-nitrophenyl)-2H-azirine

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:477249-36-8 SDS

477249-36-8Relevant articles and documents

The azomethine ylide strategy for β-lactam synthesis. Azapenams and 1-azacephams

Brown, David,Brown, Giles A.,Andrews, Mark,Large, Jonathan M.,Urban, Dominique,Butts, Craig P.,Hales, Neil J.,Gallagher, Timothy

, p. 2014 - 2021 (2002)

Reaction of the β-lactam-based oxazolidinone 5 with N-sulfonylimines provides the exo and endo azapenams 8 in 22-54% yield. The reactivity of 2H-azirines as 1,3-dipolarophiles towards β-lactam-based azomethine ylides derived from oxazolidinones 5 and 15 h

Rh(ii)-catalyzed cycloadditions of 1-tosyl 1,2,3-triazoles with 2H-azirines: Switchable reactivity of Rh-azavinylcarbene as [2C]- or aza-[3C]-synthon

Wang, Yuanhao,Lei, Xiaoqiang,Tang, Yefeng

supporting information, p. 4507 - 4510 (2015/03/18)

The Rh(ii)-catalyzed formal [3+2] and [3+3] cycloadditions of 1-tosyl 1,2,3-triazoles with 2H-azirines have been developed, which enable the efficient synthesis of polysubstituted 3-aminopyrroles and 1,2-dihydropyrazines, respectively. The reported [3+2] cycloaddition represents the first application of 1-sulfonyl 1,2,3-triazole as a [2C]-component in relevant cycloaddition reactions. This journal is

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