50639-02-6

Basic information

• Product Name: Isopentylhexyl ketone
• Synonyms: 2-Methyl-5-undecanone;Hexylisopentyl ketone;Isopentylhexyl ketone
• CAS NO: 50639-02-6
• Molecular Formula: C12H24O
• Molecular Weight: 184.3184
• Mol File: 50639-02-6.mol

Chemical Properties

• Melting Point: -11.27°C (estimate)
• Boiling Point: 243.3°C (estimate)
• Flash Point: 93.2°C
• Appearance: /
• Density: 0.8288 (estimate)
• Vapor Pressure: 0.0501mmHg at 25°C
• Refractive Index: 1.4306 (estimate)
• CAS DataBase Reference: Isopentylhexyl ketone(CAS DataBase Reference)
• NIST Chemistry Reference: Isopentylhexyl ketone(50639-02-6)
• EPA Substance Registry System: Isopentylhexyl ketone(50639-02-6)

Safety Data

• Hazardous Substances Data: 50639-02-6(Hazardous Substances Data)

Usage

InChI:InChI=1/C12H24O/c1-4-5-6-7-8-12(13)10-9-11(2)3/h11H,4-10H2,1-3H3

Upstream product

• 63859-51-8 2-methyl-undec-3t-en-5-one 
• 119072-55-8 tert-butylisonitrile 
• 18379-62-9 dihexylboron chloride 
• 7488-31-5 isoamyl lithium 
• 2783-14-4 2-nitro-1-octene 
• 100-99-2 triisobutylaluminum 
• 78-83-1 2-methyl-propan-1-ol 
• 111-13-7 hexyl-methyl-ketone 
• 16630-91-4 2-methylheptanal 

Relevant articles and documents

An Efficient Direct α-Alkylation of Ketones with Primary Alcohols Catalyzed by [Ir(cod)CI]2/PPh3/KOH System without Solvent

α-Alkylation of ketones was successfully achieved by the reaction of ketones with alcohols catalyzed by iridium complexes in the presence of a small amount of base. For example, 2-octanone was allowed to react with butanol under the influence of [Ir(cod)Cl]2/PPh3/KOH to give 6-dodecanone in good yield. The reaction was found to proceed by using a 1:1 mixture of ketone and alcohol without use of any solvent. Copyright

Efficient Conjugate Alkylation of α,β-Unsaturated Nitro Olefins by Triorganoalanes

Both trialkylaluminum (AlR3; R = Et, i-Bu) and triorganoaluminum etherates (AlR3*OEt2; R = Et, i-Bu, Ph) rapidly react with α,β-unsaturated nitro olefins to give only 1,4-monoalkylated products in high yields.The natures of substrates, the reaction conditions as well as the reagents molar ratio, do not cause significant variations on the recovered products.