52078-42-9Relevant articles and documents
PROCESS FOR PREPARING (7Z)-7-TRICOSENE
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Paragraph 0085; 0092-0100, (2020/12/05)
The present invention provides a process for preparing (7Z)-7-tricosene of the following formula (3): the process comprising a step of subjecting a nucleophilic reagent, (8Z)-8-pentadecenyl compound of the following general formula (1), wherein M1 represents Li, MgZ1, CuZ1 or CuLiZ1, wherein Z1 represents a halogen atom or an (8Z)-8-pentadecenyl group, to a coupling reaction with a 1-halooctane compound of the following general formula (2), wherein X1 represents a halogen atom, to produce (7Z)-7-tricosene (3).
Synthesis of (Z)-7-heneicosene and (Z)-7-tricosene via organoboranes - Part V
Battu, Raminderjit S.,Dhillon, Ranjit S.,Singh, Jasvinder
, p. 1104 - 1105 (2007/10/03)
(Z)-7-Heneicosene 4a and (Z)-7-tricosene 4b, the main components of the female sex pheromones of staphylinid beetle, Aleochara cartula have been synthesized by hydroboration of 1-octyne with BHBr2.SMe2 followed by esterification with a diol and subsequent treatment with Grignard reagent, I2/MeOH and NaOH.
One-pot syntheses of (Z)-7-heneicosene and (Z)-7-tricosene
Singh,Sharma,Vig,Sabharwal
, p. 486 - 486 (2007/10/02)
A new and highly sterospecific synthesis of (Z)-7-heneicosene (I) and (Z)-7-tricosene (II) through hydroboration-hydridation (LAH)-hydroboration with dibromoborane-dimethyl sulphide complex followed by iodine-induced rearrangement is described.