Sugar Enolones, XI. 2-Halopentopyranosyl Halides: Preparation, Configurational Elucidation, and Conversion into Enantiomeric Dihydropyranones
Addition of chlorine or bromine to the enediol grouping of tribenzoyl-pentenitol 2 exclusively yields cis-adducts, i.e. 1,2-dihalides of α-D-lyxo (4, 6) and β-D-xylo configuration (5, 7).Configurational assignments were based on the titanium tetrahalide-i
Lichtenthaler, Frieder W.,Sakakibara, Tohru,Egert, Ernst
p. 471 - 488
(2007/10/02)
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