524961-76-0Relevant articles and documents
The preparation and reactions of 2-acyl-3-phenylisomenthopyrazole
Kashima, Choji,Miwa, Yohei,Yokawa, Takeshi,Shibata, Saori
, p. 225 - 235 (2007/10/03)
3-Phenylisomenthopyrazole (4) was useful as a chiral auxiliary, though the diastereomeric selectivity was lower than those of 3-phenyl-l-menthopyrazole (1a). In α-acylation and the Diels-Alder cycloaddition, the absolute configuration of the predominant products was different from that of the products using 1a.
New optically active pyrazoles: Syntheses and the structural characterization of menthopyrazole analogues
Kashima, Choji,Miwa, Yohei,Shibata, Saori,Nakazono, Hiroyuki
, p. 1235 - 1240 (2007/10/03)
New chiral pyrazoles, (4R,7R)-4-methyl-7-isopropyl-3-phenyl- (3-phenylisomenthopyrazole; cis-1), (4R,7S)-4-methyl-7-isopropyl- (l-menthopyrazole; trans-2), (4R,7R)-4-isopropyl-7-methyl- (isocarvomenthopyrazole, cis-3) and (4R,7S)-4-isopropyl-7-methyl-4,5,6,7-tetrahydro-1H-indazole (carvomenthopyrazole, trans-3) were prepared. The diastereomeric pairs of these 1-3 were structurally characterized by NMR spectroscopy. The subtle differences of structures of 1-3 should induce the useful effects for a chiral auxiliary or a chiral catalyst.