cas 532391-31-4, 2-METHOXY-3-(4,4,5,5-TETRAMETHYL-[1,3,2]DIOXABOROLAN-2-YL)-PYRIDINE | Articles data ｜lookchem

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532391-31-4

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AROMATIC HETEROCYCLIC COMPOUND, INTERMEDIATE THEREOF, PREPARATION METHOD THEREFOR, AND PHARMACEUTICAL COMPOSITION AND USE THEREOF
Disclosed are an aromatic heterocyclic compound, an intermediate thereof, a preparation method therefor, and a pharmaceutical composition and use thereof. The aromatic heterocyclic compound of the present invention is a new ALK5 inhibitor, and is used for treating and/or preventing various ALK5-mediated diseases.
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Paragraph 0266-0268

(2021/02/05)

Asymmetric synthesis of 1-heteroaryl-1-arylalkyl tertiary alcohols and 1-pyridyl-1-arylethanes by lithiation-borylation methodology
The synthesis of highly enantioenriched α-heterocyclic tertiary alcohols has been achieved via lithiation-borylation of a configurationally stable lithiated carbamate and heterocyclic pinacol boronic esters followed by oxidation. Protodeboronation of the α-heterocyclic tertiary boronic esters using TBAF·3H2O or CsF gave highly enantioenriched 1-pyridyl-1-arylethanes in high er.
Watson, Charlotte G.,Aggarwal, Varinder K.
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p. 1346 - 1349
(2013/05/09)

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Chemical Properties

Appearance/Colour :yellow solid
Melting Point: 59-61°C
Boiling Point: 329.4 °C at 760 mmHg
Flash Point:153 °C
Density: 1.06 g/cm³
Vapor Pressure: 0.00034mmHg at 25°C
Refractive Index: 1.489
PKA: 3.39±0.12(Predicted)
PSA: 40.58000
LogP: 1.38940

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