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533-62-0

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Kutznerides 1-4, depsipeptides from the actinomycete Kutzneria sp. 744 inhabiting mycorrhizal roots of Picea abies seedlings
Bioassay-guided fractionation of culture supernatants of the actinomycete Kutzneria sp. 744 resulted in the isolation of four new depsipeptides (1-4). Structure analysis revealed the general structure: cyclo[2-(1-methylcyclopropyl) -D-glycine-(2S,3aR,8aS)
Broberg, Anders,Menkis, Audrius,Vasiliauskas, Rimvydas
p. 97 - 102
(2008/09/21)

L-threo- and L-erythro-3-Fluoroglutamic Acids. Synthesis by Fluorodehydroxylation and Enzymatic Resolution.
threo- and erythro-3-fluoroglutamic acids were prepared by fluorodehydroxylation of N-acetyl-3-hydroxyglutamic acids according to Kollonitsch.Following ion exchange column separation of the diastereoisomers, enzymatic deacylation by acylase I afforded optically pure L-isomers of the 3-fluoroglutamic acid.Assignment of structure was achieved by correlation with cis- and trans-3-fluoropyroglutamic acids.The results indicate predominant inversion of configuration during the fluorodehydroxylation reaction.
Vidal-Cros, Anne,Gaudry, Michel,Marquet, Andree
p. 3163 - 3167
(2007/10/02)

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Chemical Properties

Melting Point: 283 °C
Boiling Point: 440.3 °C at 760 mmHg
Flash Point:220.1 °C
Density: 1.595 g/cm³
Vapor Pressure: 1.33E-09mmHg at 25°C
Refractive Index: 1.565
PKA: 2.02±0.10(Predicted)
PSA: 120.85000
LogP: -1.06580

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