55895-85-7

Basic information

• Product Name: DIETHYL GLUTAMATE
• Synonyms: Glutamic acid, 1,5-diethyl ester
• CAS NO: 55895-85-7
• Molecular Formula: C₉H₁₇NO₄
• Molecular Weight: 203.24
• Mol File: 55895-85-7.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: DIETHYL GLUTAMATE(CAS DataBase Reference)
• NIST Chemistry Reference: DIETHYL GLUTAMATE(55895-85-7)
• EPA Substance Registry System: DIETHYL GLUTAMATE(55895-85-7)

Safety Data

• Hazardous Substances Data: 55895-85-7(Hazardous Substances Data)

Upstream product

• 64-17-5 ethanol 
• 617-65-2 Glutamic acid 

Downstream Products

• 17046-23-0 diethyl 2-isocyanatoglutarate 
• 42807-47-6 diethyl 2-benzamidopentanedioate 
• 1432740-96-9 C₁₄H₁₅NO₂ 
• 1432741-03-1 C₁₄H₁₇NO₃ 
• 1432741-08-6 ethyl 3-(5-ethoxy-2-phenyloxazol-4-yl)propanoate 
• 810-20-8 N-<4-(2-Hydroxy-indanyl-(1)-amino)-benzoyl>-DL-glutaminsaeure-diaethylester 
• 13726-52-8 diethyl N-(p-aminobenzoyl)-glutamate 
• 108952-90-5 3-(2-phenyl-1⁽³⁾H-imidazol-4-yl)-propionic acid ; hydrochloride 
• 83702-09-4 ethyl 1-benzoyl-4-(ethoxycarbonyl)-3-oxo-2-piperidinepropionate 
• 76359-12-1 (2R,4S)-1-Benzoyl-2-(2-ethoxycarbonyl-ethyl)-4-methyl-3-oxo-piperidine-4-carboxylic acid ethyl ester 
• 76359-11-0 (2S,4S)-1-Benzoyl-2-(2-ethoxycarbonyl-ethyl)-4-methyl-3-oxo-piperidine-4-carboxylic acid ethyl ester 
• 82226-54-8 1-benzoyl-4-(ethoxycarbonyl)-3-oxo-2-piperidinepropionic acid 
• 76359-22-3 (2R,4S)-1-Benzoyl-2-(2-methoxycarbonyl-ethyl)-4-methyl-3-oxo-piperidine-4-carboxylic acid ethyl ester 
• 76359-21-2 (2S,4S)-1-Benzoyl-2-(2-methoxycarbonyl-ethyl)-4-methyl-3-oxo-piperidine-4-carboxylic acid ethyl ester 

Relevant articles and documents

Process for the preparation of amino acid esters and their acid addition salts

Preparation of amino acids, peptide esters and/or their acid addition salts of monomers or polymers amino acids, peptides, proteins or alcohols (I), where the reaction is carried out in supercritical alcohols.

Process for preparing amino acid esters and their acid addition salts

The invention provides a process for preparing amino acid esters and/or their acid addition salts from monomeric or polymeric amino acids, peptides, proteins and alcohols, which comprises carrying out the reaction in supercritical alcohols, preferably at pressures and temperatures which are at least 5% above the critical parameters, the alcohols serving both as the solvent and as reactants.

2-(Ethoxycarbonylmethyl)-1H-naphtho[1,8-de]-1,2,3-triazine anion: A new glycine enolate equivalent

The titled triazine can be alkylated with LDA and a variety of alkyl halides: Subsequent reduction with aluminium amalgam cleaves the naphthotriazine moiety to afford substituted α amino acids in excellent overall yields; the sequence defines a novel methodology that can be applied under non-acidic and largely non-aqueous conditions. (C) 2000 Elsevier Science Ltd.