EVIDENCE FOR A STEREOELECTRONIC EFFECT IN THE BAEYER-VILLIGER REACTION: INTRODUCING THE INTRAMOLECULAR REACTION
An intramolecular Baeyer-Villiger reaction has been effected involving a conformationally-fixed intermediate which breaks down with stereoelectronic control.
Conformationally Restricted Criegee Intermediates: Evidence for Formation and Stereoelectronically Controlled Fragmentation
The Bayer-Villiger reaction of 2-(2-oxocyclohexyl)acetic acid occurs via a bicyclic Criegee intermediate, which fragments with stereoelectronic control, as evidenced by product analysis; the reaction of the but-2-yl ester and of 2-(2-oxocyclopentyl)acetic acid also show evidence of such stereoelectronic control, but less convincingly.
Chandrasekhar, Sosale,Roy, Chandra Deo
p. 2141 - 2144
(2007/10/02)
More Articles about upstream products of 5698-50-0