58443-86-0

Basic information

• Product Name: 1,2,5,6-TETRABROMOHEXANE
• Synonyms: 1,2,5,6-TETRABROMOHEXANE;1,2,5,6-tetrabromo-hexan;1,2,5,6-Tetrabromohexane,97%;Hexane, 1,2,5,6-tetrabromo-;1,2,5,6-TetrabroMohexane (Mixture of diastereoisoMers)
• CAS NO: 58443-86-0
• Molecular Formula: C₆H₁₀Br₄
• Molecular Weight: 401.76
• Mol File: 58443-86-0.mol

Chemical Properties

• Melting Point: 47.0 to 51.0 °C
• Boiling Point: 398.9°Cat760mmHg
• Flash Point: 189.1°C
• Appearance: /
• Density: 2.218g/cm³
• Vapor Pressure: 3.27E-06mmHg at 25°C
• Refractive Index: 1.585
• CAS DataBase Reference: 1,2,5,6-TETRABROMOHEXANE(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2,5,6-TETRABROMOHEXANE(58443-86-0)
• EPA Substance Registry System: 1,2,5,6-TETRABROMOHEXANE(58443-86-0)

Safety Data

• Statements: 20/21/22
• Safety Statements: 23-36
• TSCA: Yes
• Hazardous Substances Data: 58443-86-0(Hazardous Substances Data)

Usage

Uses

Used in Electronics Industry:
1,2,5,6-Tetrabromohexane is used as a flame retardant additive for enhancing the fire safety of electronic devices. It reduces the flammability of materials and slows down the spread of fires, thereby protecting electronic components from potential damage due to fire incidents.
Used in Plastics Industry:
In the plastics industry, 1,2,5,6-Tetrabromohexane is utilized as a flame retardant to improve the fire resistance of plastic materials. This helps in meeting safety standards and reducing the risk of fire hazards associated with plastic products.
Used in Textile Industry:
1,2,5,6-Tetrabromohexane is employed as a flame retardant in textiles to increase their fire resistance. This is particularly important for applications such as upholstery, carpets, and curtains, where fire safety is a critical concern.
However, it is important to note that 1,2,5,6-Tetrabromohexane is known to be toxic to aquatic life and may have potential adverse effects on human health, including skin and eye irritation, respiratory issues, and negative impacts on liver and thyroid function. As a result, there is growing concern about the environmental and health risks associated with its use, and efforts are being made to find safer alternatives for flame retardancy.

InChI:InChI=1/C6H10Br4/c7-3-5(9)1-2-6(10)4-8/h5-6H,1-4H2

Upstream product

• 592-42-7 1,5-Hexadien 

Downstream Products

• 72121-84-7 2-bromo-hex-1-en-5-yne 
• 628-16-0 hexa-1,5-diyne 
• 2809-69-0 2,4-hexadiyne 
• 10035-10-6 hydrogen bromide 
• 71566-70-6 2,5-dibromo-1,5-hexadiene 

Relevant articles and documents

An electron-catalyzed cope cyclization. The structure of the 2,5-dicyano-1,5-hexadiene radical anion in the gas phase

The radical anion of 2,5-dicyano-1,5-hexadiene is shown to undergo Cope cyclization in a flowing afterglow-triple quadrupole apparatus. The cyclic structure of the 2,5-dicyano-1,5-hexadiene radical anion was established by using chemical reactivity. The i

Merging shuttle reactions and paired electrolysis for reversible vicinal dihalogenations

Vicinal dibromides and dichlorides are important commodity chemicals and indispensable synthetic intermediates in modern chemistry that are traditionally synthesized using hazardous elemental chlorine and bromine. Meanwhile, the environmental persistence of halogenated pollutants necessitates improved approaches to accelerate their remediation. Here, we introduce an electrochemically assisted shuttle (e-shuttle) paradigm for the facile and scalable interconversion of alkenes and vicinal dihalides, a class of reactions that can be used both to synthesize useful dihalogenated molecules from simple alkenes and to recycle waste material through retro-dihalogenation. The reaction is demonstrated using 1,2-dibromoethane, as well as 1,1,1,2-tetrachloroethane or 1,2-dichloroethane, to dibrominate or dichlorinate, respectively, a wide range of alkenes in a simple setup with inexpensive graphite electrodes. Conversely, the hexachlorinated persistent pollutant lindane could be fully dechlorinated to benzene in soil samples using simple alkene acceptors.

En route to stable all-carbon-substituted silylenes: Synthesis and reactivity of a bis(α-spirocyclopropyl)silylene

The synthesis of a bis(α-spirocyclopropyl)silylene is reported and its reactivity revealed. Liberation of the silylene was accomplished by UV-light-mediated photolysis of a trisilane precursor. Insertion and addition reactions prove the existence and versatility of this new family of bis(α-spirocyclopropyl)-substituted silylenes. Substitution on the flanking cyclopropyls for improved steric shielding of the reactive center remains challenging.

Removal of water - a factor influencing the synthesis of alkynes in a phase-transfer catalyzed β-elimination reaction

Acetylene derivatives 4 were synthesized from the corresponding vicinal bromo compounds 2 in the phase-transfer catalyzed hydrogen bromide β-elimination reaction using solid potassium hydroxide as a base, xylene as a solvent, and a phase-transfer catalyst. The yields of the synthesized acetylene derivatives 4 were substantially improved when water formed in the process had been removed.

Enantioselective total synthesis of (+)-testudinariol A using a new nickel-catalyzed allenyl aldehyde cyclization

An enantioselective total synthesis of (+)-testudinariol A was completed. A new nickel-catalyzed allenyl aldehyde cyclization was developed in the approach. In addition, an asymmetric anti aldol reaction and a two-directional oxocarbenium ion/vinyl silane condensation were employed as key steps. Copyright