Catalyse par le palladium at la lumiere ultra-violette de l'oxydation d'alcenes par l'oxygene moleculaire
The light-promoted oxidation of terminal alkenes by oxygen in the presence of catalytic amounts of palladium(II) complexes led to corresponding α,β-ethylenic carbonyl compounds and methyl ketones; rapid and extensive isomerisation of the starting alkene is observed.The effect of acetone as solvent on the efficiency of these oxidations is discussed.
Muzart, Jacques,Pale, Patrick,Pete, Jean-Pierre
p. 267 - 274
(2007/10/02)
PHOTOACTIVATION OF ALKENE OXIDATION BY MOLECULAR OXYGEN IN THE PRESENCE OF PALLADIUM
A catalytic cycle which leads to α-β ethylenic ketones and methyl ketones from terminal alkenes in the presence of palladium trifluoroacetate, oxygen and U.V. light is described.
Muzart, Jacques,Pale, Patrick,Pete, Jean-Pierre
p. 3577 - 3578
(2007/10/02)
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