- Crystal structure of K2[C2O6] - First proof of existence and constitution of a peroxodicarbonate ion
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By using high-resolution X-ray powder diffraction, we have determined the first crystal structure of a peroxodicarbonate compound, synthesized by electrocrystallization at -20°C. The constitution of the peroxodicarbonate anion was established and all structural details, including its conformation (see picture), can be understood qualitatively in terms of classical concepts of the chemical bond.
- Dinnebier, Robert E.,Vensky, Sascha,Stephens, Peter W.,Jansen, Martin
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p. 1922 - 1924
(2007/10/03)
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- ALKALI-METAL PEROXOCARBONATES, M2*nH2O2, M2, M*nH2O, AND Li2*H2O
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The vibrational spectra of normal and(2)H-enriched carbonate perhydrates M2*nH2O2 (Na, n = 1.5; K, Rb, or Cs, n = 3; NH4, n = 1) and those of the normal and (13)C-enriched peroxodicarbonates M2 (M = Na, K, Rb, or Cs), normal and (13)C-enriched
- Jones, D. Philip,Griffith, William P.
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p. 2526 - 2532
(2007/10/02)
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