cas 60549-26-0, 3-Hydroxy-5-Methylbenzaldehyde | Articles data ｜lookchem

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60549-26-0

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NOVEL METAL FREE PROCESS FOR ALLYLIC OXIDATION
The patent discloses a novel metal free process for the preparation of corresponding phenol and ketone via allylic oxidation of substituted cyclohexenes. Air is used as oxidant in the present process and can be used as such or optionally selected from pure oxygen or atmospheric oxygen. Moreover, the process of the present invention utilizes easily available starting materials and is a green eco-friendly, convenient and economical process with high yield of >60 % and high selectivity
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Page/Page column 10

(2015/02/25)

Roles of the synergistic reductive O-methyltransferase GilM and of O-methyltransferase GilMT in the gilvocarcin biosynthetic pathway
Two enzymes of the gilvocarcin biosynthetic pathway, GilMT and GilM, with unclear functions were investigated by in vitro studies using purified, recombinant enzymes along with synthetically prepared intermediates. The studies revealed GilMT as a typical
Tibrewal, Nidhi,Downey, Theresa E.,Van Lanen, Steven G.,Ul Sharif, Ehesan,O'Doherty, George A.,Rohr, Juergen
supporting information; experimental part
p. 12402 - 12405
(2012/09/05)

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Chemical Properties

Melting Point: 107-108 °C(Solv: chloroform (67-66-3))
Boiling Point: 259.2±20.0 °C(Predicted)
Density: 1.175±0.06 g/cm3(Predicted)
Storage Temp.:under inert gas (nitrogen or Argon) at 2-8°C
PKA: 9.35±0.10(Predicted)
PSA: 37.30000
LogP: 1.51310

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