605686-13-3

Basic information

• Product Name: 1-Indanone,hexahydro-7-methyl-,trans-(7CI)
• Synonyms: 1-Indanone,hexahydro-7-methyl-,trans-(7CI)
• CAS NO: 605686-13-3
• Molecular Formula: C10H16O
• Molecular Weight: 152.23
• Product Categories: CYCLOPENTANE
• Mol File: 605686-13-3.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1-Indanone,hexahydro-7-methyl-,trans-(7CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Indanone,hexahydro-7-methyl-,trans-(7CI)(605686-13-3)
• EPA Substance Registry System: 1-Indanone,hexahydro-7-methyl-,trans-(7CI)(605686-13-3)

Safety Data

• Hazardous Substances Data: 605686-13-3(Hazardous Substances Data)

Upstream product

• 83586-04-3 7t-Methyl-(3arH,7atH)-3a,4,7,7a-tetrahydro-indanon-⁽¹⁾ 
• 2004-70-8 1-methylbuta-1,3-diene 
• 34164-50-6 4-penten-1-ylmagnesium bromide 
• 22627-73-2 3--cyclopentanon 
• 23830-94-6 3-(4-Brom-pentyl)-cyclopentanon 
• 22627-62-9 3-(4-pentenyl)-2-methyl-2-cyclopentenone 
• 22627-64-1 2-Methyl-3-(penten-4-yl)-cyclopentanon 
• 605686-10-0 7t-Methyl-(3arH,7acH)-3a,4,7,7a-tetrahydro-indanon-⁽¹⁾ 
• 930-30-3 cyclopent-2-enone 
• 22627-65-2 2-Methyl-3-(4-brom-pentyl)-cyclopentanon 
• 103263-08-7 1-(6-Methyl-cyclohex-3-enyl)-1-hydroxy-propan-2-on 
• 21197-29-5 3-(3-methyl-2-oxo-cyclohexyl)-propionitrile 
• 90925-18-1 7-Methyl-3a,6,7,7a-tetramethyl-indan-1-on 

Relevant articles and documents

Electroorganic Chemistry. 140. Electroreductively Intra- and Intermolecular Couplings of Ketones with Nitriles

Electroreduction of γ- and δ-cyano ketones in i-PrOH with Sn cathode gave α-hydroxy ketones and their dehydroxylated ketones as the intramolecularly coupled products.Guaiazulene, (-)-valeranone, polyquinanes, dihydrojasmone, methyl dihydrojasmonate, and rosaprostol have been synthesized by utilizing this electroreductive intramolecular coupling of γ- and δ-cyano ketones in one of the key steps.Similarly, electroreduction of a mixture of ketone and nitrile gave the corresponding intermolecularly coupled product.The product obtained by the electroreductive intermolecular coupling of (+)-dihydrocarvone with acetonitrile has been found to be the precursor of an effective chiral ligand for the enantioselective addition of diethylzinc to aldehydes.

Silicon-Directed Nazarov Reactions III. Stereochemical and Mechanistic Considerations

The influence of remote substituents on the stereochemical outcome of electrocyclization in the silicon-directed Nazarov reaction has been examined.While the degree of stereocontrol was modest (ca. 3:1) the substituent in the major isomer (4,5 or 7-substi

Diels-Alder Reactions of Cycloalkenones. 1. Preparation and Structure of the Adducts

Uncatalyzed and aluminum chloride induced Diels-Alder reactions of 2-cyclopentenones, 2-cyclohexenones, and 2-cycloheptenones with 1,3-butadiene, isoprene, and (E)-piperylene are described.Structure analysis of the adducts and their hydrogenation products by standard means and 13C NMR spectroscopy is presented.