- Copper(II) Complexes of Cyclams Containing Nitrophenyl Substituents: Push-Pull Behavior and Scorpionate Coordination of the Nitro Group
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The three nitrophenyl-cyclam derivatives (nitrocyclams): 1-(4-nitrophenyl)-1,4,8,11-tetraazacyclotetradecane (2), 1-(2-nitrophenyl)-1,4,8,11-tetraazacyclotetradecane (3), and 1-(2,4-dinitrophenyl)-1,4,8,11-tetraazacyclotetradecane (4), in an MeCN solution
- Boiocchi, Massimo,Ciarrocchi, Carlo,Fabbrizzi, Luigi,Licchelli, Maurizio,Mangano, Carlo,Poggi, Antonio,Vázquez López, Miguel
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- A two-channel molecular dosimeter for the optical detection of copper(II)
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A cyclam-like macrocycle with an integrated push-pull chromophore selectively detects Cu2+ inclusion through both orange-to-yellow colour change and quenching of the green fluorescence.
- Boiocchi, Massimo,Fabbrizzi, Luigi,Licchelli, Maurizio,Sacchi, Donatella,Vazquez, Miguel,Zampa, Cristina
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p. 1812 - 1813
(2007/10/03)
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