615564-54-0

Basic information

• Product Name: 1-(Ph₂N)-2-[B(C₆F₅)2]C₆H₄
• Synonyms: 1-(Ph₂N)-2-[B(C₆F₅)2]C₆H₄
• CAS NO: 615564-54-0
• Molecular Weight: 589.243
• Mol File: 615564-54-0.mol

Chemical Properties

• CAS DataBase Reference: 1-(Ph₂N)-2-[B(C₆F₅)2]C₆H₄(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(Ph₂N)-2-[B(C₆F₅)2]C₆H₄(615564-54-0)
• EPA Substance Registry System: 1-(Ph₂N)-2-[B(C₆F₅)2]C₆H₄(615564-54-0)

Safety Data

• Hazardous Substances Data: 615564-54-0(Hazardous Substances Data)

Upstream product

• 2720-03-8 bis(pentafluorophenyl)boron chloride 
• 78600-31-4 N-(2-bromophenyl)-N-phenylbenzenamine 
• 122-39-4 diphenylamine 
• 583-55-1 1-Bromo-2-iodobenzene 

Downstream Products

• 615564-57-3 [1-(Ph₂N)-2-(B(H)(C₆F₅)2)C₆H₄][Li(12-crown-4)] 
• 1109-15-5 tris(pentafluorophenyl)borate 
• 615564-58-4 1-(Ph₂NH)-2-[B(Cl)(C₆F₅)2]C₆H₄ 

Relevant articles and documents

Synthesis, structural characterization and reactivity of the amino borane 1-(NPh2)-2-[B(C6F5) 2]C6H4

The bright red title compound 1 was synthesized from (2-lithiophenyl) diphenylamine and bis(pentafluorophenyl)boron chloride. Its reactions with small acids like H2O and HCl proceeded easily giving zwitterionic compounds. For 1 and its water adduct 2 the crystal structures were determined, the latter featuring an ammonium borate structure containing a short intramolecular hydrogen bond bridge. Treatment of 1 with Jutzi's acid, [H(OEt2)2] [B(C6F5)4], did not result in protonation of the nitrogen, but reaction of 1 with LiH in the presence of 12-crown-4, led to the isolation of the aminoborate [1-(Ph2N)-2-{B(H)(C6F5)2} C6H4][Li(12-crown-4)] (3). Borohydride 3 reacted with Jutzi's acid to regenerate 1 and liberate hydrogen.