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Diphenylamine 122-39-4 /manufacturer/low price/high quality/in stock
Cas No: 122-39-4
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High purity Diphenylamine CAS:122-39-4
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diphenylamine
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Good quality Diphenylamine
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TIANFU-CHEM Diphenylamine, pure, 99%
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Diphenylamine
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Diphenylamine with CAS:122-39-4
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122-39-4 Usage

Reactivity Profile

Diphenylamine discolors in light. Diphenylamine can react violently with hexachloromelamine and trichloromelamine. Diphenylamine is incompatible with strong oxidizing agents and strong acids. Diphenylamine is also incompatible with iron and silver salts. Diphenylamine reacts with nitrogen oxides.

Air & Water Reactions

Dust may be explosive if mixed with air in critical proportions and in the presence of a source of ignition [USCG, 1999]. Insoluble in water.

Uses

Diphenylamine is an aromatic amine that was shown to exhibit antioxidant activities and is now used as an anti-scald agent. It is also used in the manufacture of a variety of substances, for instance, dye stuffs and their intermediates, pesticides, anthelmintic drugs, and as reagents in analytical chemistry laboratories.

Definition

ChEBI: An aromatic amine containing two phenyl substituents. It has been used as a fungicide for the treatment of superficial scald in apples and pears, but is no longer approved for this purpose within the European Union.

Agricultural Uses

Insecticide, Fungicide, Herbicide, Plant growth regulator: Topically in anti-screwworm mixtures, foliar application in a modified growth chamber to decrease ozone injury to leaves of apple, bean, muskmelon, petunia, and tobacco plants. To control weather fleck in tobacco and inhibit algae formation. To prolong the fresh appearance of snapdragons. Protect rice from the toxic effects of thiolcarbamate herbicides [83] . Not currently approved for use in EU countries (resubmitted) . Registered for use in the U.S. and other countries.

Trade name

NO- SCALD DPA 31; NO- SCALD DPA 283; SCALDIP; Z-876

Health Hazard

Inhalation may irritate mucous membranes. Overexposure, including ingestion of solid or skin contact, may cause fast pulse, hypertension, and bladder trouble. Contact with dust irritates eyes.

General Description

Light tan to brown solid with a pleasant odor. Sinks in water.

Purification Methods

Crystallise diphenylamine from pet ether, MeOH, or EtOH/water. Dry it under vacuum. [Beilstein 12 H 174, 12 IV 271.]

Chemical Properties

white crystals or powder
InChI:InChI=1/C12H11N/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12/h1-10,13H

122-39-4 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Sigma-Aldrich (33149)  Diphenylamine  puriss. p.a., redox indicator, ACS reagent, reag. Ph. Eur., ≥98% (GC) 122-39-4 33149-100G-R 1,186.38CNY Detail
Sigma-Aldrich (45456)  Diphenylamine  PESTANAL®, analytical standard 122-39-4 45456-250MG 180.18CNY Detail
Alfa Aesar (36610)  Diphenylamine, ACS    122-39-4 500g 1264.0CNY Detail
Alfa Aesar (36610)  Diphenylamine, ACS    122-39-4 100g 381.0CNY Detail
Alfa Aesar (36610)  Diphenylamine, ACS    122-39-4 25g 144.0CNY Detail
Alfa Aesar (A18265)  Diphenylamine, 98+%    122-39-4 2500g 1557.0CNY Detail
Alfa Aesar (A18265)  Diphenylamine, 98+%    122-39-4 500g 366.0CNY Detail
Alfa Aesar (A18265)  Diphenylamine, 98+%    122-39-4 100g 191.0CNY Detail

122-39-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name diphenylamine

1.2 Other means of identification

Product number -
Other names Diphenylamine,Redox-indicator

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Intermediates
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:122-39-4 SDS

122-39-4Synthetic route

bromobenzene
108-86-1

bromobenzene

aniline
62-53-3

aniline

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With sodium t-butanolate; tri tert-butylphosphoniumtetrafluoroborate; Pd{dba(OMe)}2 In toluene at 25℃; for 0.166667h; Buchwald-Hartwig cross coupling reaction;100%
With potassium ethoxide In 1,4-dioxane at 200℃; Catalytic behavior; Buchwald-Hartwig Coupling;100%
With C31H26N4PPdS(1+)*Cl(1-); sodium t-butanolate In toluene at 95℃; for 14h; Catalytic behavior;100%
N-cyclohexylidenebenzenamine
1132-38-3

N-cyclohexylidenebenzenamine

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
palladium-carbon In diethylene glycol dimethyl ether; water; nitrobenzene; benzene100%
palladium-carbon In water; nitrobenzene; benzene100%
palladium-carbon In diethylene glycol dimethyl ether; water; nitrobenzene; benzene100%
diphenylformamide
607-00-1

diphenylformamide

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With tetra(n-butyl)ammonium hydroxide In tetrahydrofuran; water for 0.166667h; Ambient temperature;100%
With potassium phosphate; C29H55FeNOP2; hydrogen In tetrahydrofuran at 110℃; under 15001.5 Torr; for 3h; Catalytic behavior;99%
With C18H37ClMoNO2P2; hydrogen; sodium triethylborohydride In tetrahydrofuran; toluene at 100℃; under 37503.8 Torr; for 24h; Autoclave; Glovebox;86%
With [bis({2‐[bis(propan‐2‐yl)phosphanyl]ethyl})amide](carbonyl)(hydride)iron(II); hydrogen In tetrahydrofuran at 100℃; under 22801.5 Torr; for 4h; Catalytic behavior;
iodobenzene
591-50-4

iodobenzene

aniline
62-53-3

aniline

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
[1,3-{bis-N-(N-methylimidazolylidene)methyl}-5-methylbenzenecopper dibromide]; caesium carbonate at 170℃; for 12h; Conversion of starting material;100%
[(N,N-dipyridyl-imidazolylidene)copper dibromide]; caesium carbonate at 170℃; for 12h; Conversion of starting material;100%
With C31H26N4PPdS(1+)*Cl(1-); sodium t-butanolate In toluene at 95℃; for 10h; Catalytic behavior;100%
aniline
62-53-3

aniline

phenylboronic acid
98-80-6

phenylboronic acid

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With 2,6-dimethylpyridine; fac-tris(2-phenylpyridinato-N,C2')iridium(III); copper diacetate; n-tetradecanoic acid In toluene; acetonitrile at 35℃; for 20h; Chan-Lam Coupling; Irradiation;100%
With copper diacetate; potassium carbonate; benzoic acid In ethyl acetate at 80℃; for 4h; air;98%
With potassium carbonate In water at 20℃; Reagent/catalyst; Solvent;95%
diphenyl-carbamic acid allyl ester

diphenyl-carbamic acid allyl ester

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With aminomethyl resin-supported N-propylbarbituric acid; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran at 20℃; for 1h;100%
1N-NaOH

1N-NaOH

N-cyclohexylidenebenzenamine
1132-38-3

N-cyclohexylidenebenzenamine

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
palladium-carbon In diethylene glycol dimethyl ether; water; nitrobenzene; benzene100%
palladium-carbon In diethylene glycol dimethyl ether; water; nitrobenzene; benzene100%
palladium-carbon In water; nitrobenzene; benzene99.4%
palladium-carbon In water; nitrobenzene; benzene99.4%
1-tert-butyl-1,1-dimethyl-N,N-diphenylsilanamine
1321455-60-0

1-tert-butyl-1,1-dimethyl-N,N-diphenylsilanamine

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With silica gel In ethanol; water at 20℃; for 2h;100%
aniline
62-53-3

aniline

phenylmagnesium bromide
100-58-3

phenylmagnesium bromide

A

biphenyl
92-52-4

biphenyl

B

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
Stage #1: aniline With n-butyllithium; dichloro(N,N,N’,N‘-tetramethylethylenediamine)zinc In tetrahydrofuran; hexane at 0 - 20℃; for 0.5h; Inert atmosphere; Schlenk technique;
Stage #2: phenylmagnesium bromide With 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; bis(acetylacetonate)nickel(II); 1,2-dichloro-2-methylpropane In tetrahydrofuran; hexane at 0 - 20℃; for 3h; Inert atmosphere; Schlenk technique;
A n/a
B 100%
aniline
62-53-3

aniline

chlorobenzene
108-90-7

chlorobenzene

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With sodium t-butanolate; 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride; Ni(PPh3)2(1-(p-acetylnaphthyl))Cl In 1,4-dioxane at 100℃;99%
With bis(η3-allyl-μ-chloropalladium(II)); potassium tert-butylate; 1,3-bis[(2,6-diisopropyl)phenyl]imidazolinium chloride In 1,4-dioxane at 100℃; for 1.5h; Inert atmosphere;99%
With sodium t-butanolate In toluene at 110℃; Inert atmosphere; Glovebox; chemoselective reaction;99%
triphenylbismuth bis(trifluoroacetate)
28719-46-2

triphenylbismuth bis(trifluoroacetate)

aniline
62-53-3

aniline

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
copper In dichloromethane for 0.5h; Ambient temperature;99%
toluene-4-sulfonic acid phenyl ester
640-60-8

toluene-4-sulfonic acid phenyl ester

aniline
62-53-3

aniline

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With (1,3-bis(2,6-diisopropylphenyl)imidazolidene)Ni(styrene)2; lithium tert-butoxide In 1,4-dioxane for 10h; Inert atmosphere; Heating; Schlenk technique;99%
With potassium hydroxide; [(N,N-dimethylbenzylamine)(trifluoroacetato)palladium(II)]2; XPhos In water at 80℃; for 16h;91%
With di-tert-butyl{2′-isopropoxy-[1,1′-binaphthalen]-2-yl}phosphane; potassium phosphate; palladium diacetate; phenylboronic acid In butan-1-ol at 110℃; for 2h; Inert atmosphere;99 %Chromat.
N,N-diphenylbenzamide
4051-56-3

N,N-diphenylbenzamide

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With potassium phosphate; C29H55FeNOP2; hydrogen In tetrahydrofuran at 130℃; under 37503.8 Torr; for 3h; Catalytic behavior;99%
With triethyl borane; sodium hydroxide In tert-butyl methyl ether at 80℃; for 6h; Inert atmosphere; Sealed tube;78%
Stage #1: N,N-diphenylbenzamide With Triethoxysilane; sodium triethylborohydride In tert-butyl methyl ether at 80℃; for 6h;
Stage #2: With hydrogenchloride In tert-butyl methyl ether; water at 20℃; for 1h; chemoselective reaction;
73%
Multi-step reaction with 2 steps
1: potassium hydroxide; triethyl borane / tetrahydrofuran / 24 h / 100 °C / Inert atmosphere; Schlenk technique; Sealed tube
2: sodium hydroxide; water / tetrahydrofuran / 1 h / 25 °C / Inert atmosphere; Schlenk technique; Sealed tube
View Scheme
10H-phenothiazine
92-84-2

10H-phenothiazine

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With 3-Hydroxy-1-methylpiperidine; nickel diacetate; sodium hydride In tetrahydrofuran at 65℃; for 4h;98%
With sodium tetrahydroborate; nickel dichloride In tetrahydrofuran; methanol for 1h; Mechanism; Ambient temperature; kinetic isotope effect; desulfurization of other benzo- and dibenzothiophenes;68%
bei der Zinkstaub-Destillation;
4-[(diphenylamino)-methyl]-benzonitrile

4-[(diphenylamino)-methyl]-benzonitrile

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With Triethylgermyl-natrium In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide at 60℃; for 68h;98%
Phenyl triflate
17763-67-6

Phenyl triflate

aniline
62-53-3

aniline

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With C46H27F24FeNiP2(1+)*CF3O3S(1-); triethylamine In 2-methyltetrahydrofuran at 100℃; for 16h; Solvent; Reagent/catalyst; Inert atmosphere; Schlenk technique; Glovebox; Sealed tube;98%
With [(2,6-bis(2,4,6-triisopropylphenyl)phenyl)dicyclohexylphosphine](allyl-η3)palladium(II) chloride; potassium hydrogencarbonate In dodecane; tert-butyl alcohol at 100℃; for 12h; Inert atmosphere; Sealed tube;92%
With caesium carbonate; palladium diacetate In toluene at 100℃; for 10h;
With palladium diacetate; caesium carbonate; XPhos In toluene at 100℃; for 1.5h;
With XPhos; palladium diacetate; caesium carbonate In toluene at 20 - 100℃; Inert atmosphere;
bromobenzene
108-86-1

bromobenzene

Ph5FcP(t-BU)2

Ph5FcP(t-BU)2

Pd(dba)2/Ph5FcP(t-Bu)2

Pd(dba)2/Ph5FcP(t-Bu)2

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With aniline; sodium t-butanolate; Pd(dba)2 In chlorobenzene; toluene98%
phenol
108-95-2

phenol

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With palladium on activated carbon; ammonium formate; lithium hydroxide In m-xylene at 160℃; for 24h; Catalytic behavior; Reagent/catalyst; Solvent; Temperature; Schlenk technique; Inert atmosphere;98%
Multi-step reaction with 2 steps
1: Inert atmosphere
2: bis(1,5-cyclooctadiene)nickel(0); sodium t-butanolate; 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride / 1,4-dioxane / 3 h / 80 °C / Inert atmosphere
View Scheme
With ammonium formate In 1,3,5-trimethyl-benzene at 140℃; under 760.051 Torr; Reagent/catalyst; Solvent; Temperature; Inert atmosphere;73 %Chromat.
iodobenzene
591-50-4

iodobenzene

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With L-arginine; potassium hydroxide In water at 80℃; under 760.051 Torr; for 2h; Reagent/catalyst; Solvent; Temperature; Green chemistry;98%
With potassium phosphate; copper(l) iodide; lithium amide In N,N-dimethyl-formamide at 130℃; for 24h; Inert atmosphere; chemoselective reaction;90%
Multi-step reaction with 2 steps
1: ammonia / water / 16 h / 75 °C / Ionic liquid
2: Cu2O nanoparticles (Cu2O-NPs) synthesized in n-Bu4POAc from CuCO3 / 16 h / 75 °C / Ionic liquid
View Scheme
N-carbobenzyloxydiphenylamine
102078-86-4

N-carbobenzyloxydiphenylamine

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With N1,N1,N12,N12-tetramethyl-7,8-dihydro-6H-dipyrido[1,2-a:2,1'-c][1,4]diazepine-2,12-diamine In N,N-dimethyl-formamide for 72h; Inert atmosphere; Glovebox; UV-irradiation;98%
phenyl methanesulfonate
16156-59-5

phenyl methanesulfonate

aniline
62-53-3

aniline

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With potassium phosphate; bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)]; N-[2-(di(1-adamantyl)phosphino)phenyl]morpholine In 1,4-dioxane; tert-butyl alcohol at 110℃; Buchwald-Hartwig Coupling; Inert atmosphere; Glovebox; chemoselective reaction;98%
phenyl N,N-dimethylsulfamate
66950-63-8

phenyl N,N-dimethylsulfamate

aniline
62-53-3

aniline

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With sodium t-butanolate In ethylene glycol at 100℃; for 12h;97%
With 1,1'-bis-(diphenylphosphino)ferrocene; bis(1,5-cyclooctadiene)nickel(0); sodium t-butanolate In toluene at 20 - 105℃; Inert atmosphere;94%
With bis(1,5-cyclooctadiene)nickel(0); sodium t-butanolate; 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride In 1,4-dioxane at 80℃; for 3h; Inert atmosphere;77%
With sodium t-butanolate; bis(1,5-cyclooctadiene)nickel (0); 1,3-bis[(2,6-diisopropyl)phenyl]imidazolinium chloride In 1,4-dioxane at 80℃; for 3h; Inert atmosphere;77%
With (1,2-dimethoxyethane)dichloronickel(II); 2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole; sodium t-butanolate; 1,3-bis[(2,6-diisopropyl)phenyl]imidazolinium chloride In 1,4-dioxane at 23 - 80℃; for 4h; Inert atmosphere;63%
triphenyltin chloride
639-58-7

triphenyltin chloride

aniline
62-53-3

aniline

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With triethylamine at 95℃; Catalytic behavior; Reagent/catalyst; Temperature;97%
With triethylamine at 90℃; for 12h; Reagent/catalyst; Temperature; Stille Cross Coupling;96%
With triethylamine at 20℃; for 15h; Catalytic behavior; Temperature;95%
With copper diacetate; triethylamine at 20℃; for 24h;94%
N,N-diphenylacetamide
519-87-9

N,N-diphenylacetamide

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With potassium phosphate; C29H55FeNOP2; hydrogen In tetrahydrofuran at 110℃; under 22502.3 Torr; for 3h; Catalytic behavior;96%
With triethyl borane; sodium hydroxide In tert-butyl methyl ether at 80℃; for 6h; Inert atmosphere; Sealed tube;89%
Stage #1: N,N-diphenylacetamide With Triethoxysilane; sodium triethylborohydride In tert-butyl methyl ether at 80℃; for 6h;
Stage #2: With hydrogenchloride In tert-butyl methyl ether; water at 20℃; for 1h; chemoselective reaction;
83%
triphenylbismuth(V) diacetate
28899-97-0

triphenylbismuth(V) diacetate

aniline
62-53-3

aniline

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
copper In dichloromethane for 2h; Ambient temperature;96%
With copper(II) dipivaloate In dichloromethane for 0.0833333h; Ambient temperature;100 % Chromat.
N,N-diphenylpyridine-2-sulfonamide
370839-63-7

N,N-diphenylpyridine-2-sulfonamide

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With magnesium In methanol at 0℃; for 1h;96%
iodobenzene
591-50-4

iodobenzene

aniline
62-53-3

aniline

A

N,N-diphenylaminobenzene
603-34-9

N,N-diphenylaminobenzene

B

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With [2,2]bipyridinyl; potassium tert-butylate; copper(l) iodide In toluene at 115℃; for 3.5h; Product distribution; Further Variations:; Reagents;A 95%
B 2%
With copper at 180℃; for 12h;A 46%
B 31%
With copper(l) iodide; cesium fluoride In dimethyl sulfoxide at 130℃; for 24h; Ullmann Condensation; Inert atmosphere; Glovebox;A 12%
B 39 %Chromat.
With potassium tert-butylate; copper(l) iodide; tributylphosphine In toluene at 110℃; for 3.5h; Product distribution; Further Variations:; Catalysts; high pressure;
N,N-diphenylacetamide
519-87-9

N,N-diphenylacetamide

A

ethanol
64-17-5

ethanol

B

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With hydrogen In toluene at 160℃; under 45004.5 Torr; for 15h; Catalytic behavior; Autoclave;A 89 %Chromat.
B 95%
With cis-[Ru(CH3CN)2(η3-C3H5)(CO1,5-cyclooctadiene)]BF4; hydrogen; potassium hexamethylsilazane; (2-aminoethyl)diphenylphosphane In tetrahydrofuran at 100℃; under 38002.6 Torr; for 24h; Autoclave;
With {Ru(H)(BH4)(CO)(3-(di-tert-butylphosphino)-N-((1-methyl-1H-imidazol-2-yl)methyl)propylamine)}; hydrogen In isopropyl alcohol at 120℃; under 22502.3 Torr; for 18h; Autoclave;A 96 %Chromat.
B 96 %Chromat.
With C16H25MnN3O3P(1+)*Br(1-); potassium tert-butylate; hydrogen In cyclohexane at 100℃; under 22502.3 Torr; for 16h; Inert atmosphere; Autoclave;A 80 %Chromat.
B 82 %Chromat.
N,N-diphenyloctanamide
1369416-85-2

N,N-diphenyloctanamide

A

octanol
111-87-5

octanol

B

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With hydrogen; sodium methylate; [carbonylchlorohydrido{bis[2-(diphenylphosphinomethyl)ethyl]amino}ethylamino] ruthenium(II) In methanol at 100℃; under 37503.8 Torr; for 16h; Autoclave;A 77%
B 95%
bromocyane
506-68-3

bromocyane

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With trimethylamine Ambient temperature;100%
With magnesium carbonate In water; acetonitrile for 288h; Heating;54%
diphenylamine
122-39-4

diphenylamine

chloroacetyl chloride
79-04-9

chloroacetyl chloride

2-chloro-N,N-diphenylacetamide
5428-43-3

2-chloro-N,N-diphenylacetamide

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 20℃; for 0.333333h;100%
In toluene at 90℃; for 4h; Inert atmosphere;99%
In N,N-dimethyl-formamide at 80℃; for 2h;97%
diphenylamine
122-39-4

diphenylamine

bis(4-bromophenyl)amine
16292-17-4

bis(4-bromophenyl)amine

Conditions
ConditionsYield
With N-Bromosuccinimide Bromination;100%
With N-Bromosuccinimide In N,N-dimethyl-formamide at 0℃; for 6h; Inert atmosphere;100%
With tetra-N-butylammonium tribromide In chloroform for 0.0333333h; Ambient temperature;99%
diphenylamine
122-39-4

diphenylamine

N-nitrosodiphenylamine
382165-80-2

N-nitrosodiphenylamine

Conditions
ConditionsYield
With oxalic acid; sodium nitrite In dichloromethane for 5h; Ambient temperature;100%
With [NO(1+)*18-crown-6*H(NO3)2(1-)] In dichloromethane at 20℃; for 0.0833333h;100%
With sodium azide In water; acetonitrile at 20℃;100%
carbon disulfide
75-15-0

carbon disulfide

diphenylamine
122-39-4

diphenylamine

lithium N,N-diphenyl dithiocarbamate
112492-65-6

lithium N,N-diphenyl dithiocarbamate

Conditions
ConditionsYield
With lithium derivative In water; toluene; benzene for 2h;100%
Stage #1: diphenylamine With Lithium dimsyl In tetrahydrofuran at 0℃; for 0.5h;
Stage #2: carbon disulfide In tetrahydrofuran at 0 - 20℃; for 12h; Reagent/catalyst;
98%
With n-butyllithium 1) hexane, -78 deg C to RT, 2) -78 deg C to RT; Multistep reaction;
Stage #1: diphenylamine With n-butyllithium In tetrahydrofuran at 0 - 20℃; for 0.5h;
Stage #2: carbon disulfide In tetrahydrofuran at 0 - 12℃; for 12h;
Stage #1: diphenylamine With n-butyllithium In tetrahydrofuran at 0℃; for 0.5h;
Stage #2: carbon disulfide In tetrahydrofuran at 0 - 20℃; for 12h;
pentafluorosulfanyl isocyanate
2375-30-6

pentafluorosulfanyl isocyanate

diphenylamine
122-39-4

diphenylamine

N'-(Pentafluorosulfanyl)-N,N-diphenylurea
90598-10-0

N'-(Pentafluorosulfanyl)-N,N-diphenylurea

Conditions
ConditionsYield
In chloroform100%
diphenylamine
122-39-4

diphenylamine

diphenylamine; deprotonated form
61057-05-4

diphenylamine; deprotonated form

Conditions
ConditionsYield
With NaH-cryptand<2.2.1> In tetrahydrofuran for 0.166667h;100%
1-bromo-4-tert-butylbenzene
3972-65-4

1-bromo-4-tert-butylbenzene

diphenylamine
122-39-4

diphenylamine

N,N-diphenyl-N-(4-tert-butylphenyl)amine
36809-23-1

N,N-diphenyl-N-(4-tert-butylphenyl)amine

Conditions
ConditionsYield
With bis(tri-t-butylphosphine)palladium(0); potassium tert-butylate In toluene at 20℃; for 4h;100%
With palladium diacetate; P(i-BuNCH2CH2)3N; sodium t-butanolate In toluene at 80℃;96%
for 3h;96%
diphenylamine
122-39-4

diphenylamine

diphenyl acetylene
501-65-5

diphenyl acetylene

((E)-1,2-Diphenyl-vinyl)-diphenyl-amine
134414-84-9

((E)-1,2-Diphenyl-vinyl)-diphenyl-amine

Conditions
ConditionsYield
phosphazene base-P4-tert-butyl In hexane; dimethyl sulfoxide at 120℃; for 24h;100%
2-chloropyridine
109-09-1

2-chloropyridine

diphenylamine
122-39-4

diphenylamine

2-N,N-diphenylaminopyridine
50910-08-2

2-N,N-diphenylaminopyridine

Conditions
ConditionsYield
With sodium t-butanolate; tris(dibenzylideneacetone)dipalladium (0); P(i-BuNCH2CH2)3N In toluene at 100℃; for 20h; Buchwald-Hartwig amination;100%
With palladium diacetate; sodium t-butanolate; ruphos In neat (no solvent) at 110℃; for 12h; Buchwald-Hartwig Coupling; Green chemistry;99%
With (1,3-bis(2,6-diisopropylphenyl)-3,4,5,6-tetrahydropyrimidin-2-ylidene)Pd(cinnamyl, 3-phenylallyl)Cl; sodium t-butanolate In neat (no solvent) at 110℃; for 12h; Buchwald-Hartwig Coupling; Inert atmosphere; Green chemistry;99%
bromochlorobenzene
106-39-8

bromochlorobenzene

diphenylamine
122-39-4

diphenylamine

(p-chlorophenyl)diphenylamine
4316-56-7

(p-chlorophenyl)diphenylamine

Conditions
ConditionsYield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; palladium 10% on activated carbon; sodium t-butanolate In 1,3,5-trimethyl-benzene for 24h; Inert atmosphere; Reflux;100%
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene at 80℃;90.7%
With tris-(dibenzylideneacetone)dipalladium(0); johnphos; sodium t-butanolate In toluene at 100℃; for 24h; Buchwald-Hartwig Coupling; Sealed tube; Inert atmosphere;79%
diphenylamine
122-39-4

diphenylamine

allyl bromide
106-95-6

allyl bromide

N-allyldiphenylamine
65178-51-0

N-allyldiphenylamine

Conditions
ConditionsYield
With tetra-(n-butyl)ammonium iodide; potassium carbonate In acetonitrile Reflux;100%
With tetra-(n-butyl)ammonium iodide; potassium carbonate In acetonitrile Reflux;100%
With tetra-(n-butyl)ammonium iodide; potassium carbonate In acetonitrile at 110℃; Inert atmosphere;81%
(chloromethyl)methoxydimethylsilane
18143-33-4

(chloromethyl)methoxydimethylsilane

diphenylamine
122-39-4

diphenylamine

N-{[dimethyl(methoxy)silyl]methyl}-N',N'-diphenyl-urea

N-{[dimethyl(methoxy)silyl]methyl}-N',N'-diphenyl-urea

Conditions
ConditionsYield
In toluene at 80℃; for 2h;100%
diphenylamine
122-39-4

diphenylamine

4'-biphenyl chloride
2051-62-9

4'-biphenyl chloride

N,N-bis(phenyl)-4-biphenylamine
4432-94-4

N,N-bis(phenyl)-4-biphenylamine

Conditions
ConditionsYield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; palladium 10% on activated carbon; sodium t-butanolate In 1,3,5-trimethyl-benzene for 24h; Inert atmosphere; Reflux;100%
Stage #1: diphenylamine; 4'-biphenyl chloride With palladium diacetate; sodium sulfate; sodium t-butanolate; XPhos for 1h; Buchwald-Hartwig Coupling; Milling;
Stage #2: In water; ethyl acetate for 0.0333333h; Reagent/catalyst; Buchwald-Hartwig Coupling; Milling;
51%
diphenylamine
122-39-4

diphenylamine

C12H10N(1-)*K(1+)*0.5C4H8O

C12H10N(1-)*K(1+)*0.5C4H8O

Conditions
ConditionsYield
With potassium hydride In tetrahydrofuran at 50℃; for 6h; Schlenk technique; Inert atmosphere;100%
undec-10-enoyl chloride
38460-95-6

undec-10-enoyl chloride

diphenylamine
122-39-4

diphenylamine

N,N-diphenylundec-10-enamide
52007-57-5

N,N-diphenylundec-10-enamide

Conditions
ConditionsYield
In toluene for 3h; Reflux; Inert atmosphere;100%
hydrogen tetrakis(3,5-bis(trifluoromethyl)phenyl)borate
121281-53-6

hydrogen tetrakis(3,5-bis(trifluoromethyl)phenyl)borate

diphenylamine
122-39-4

diphenylamine

C12H11N*H(1+)*C32H12BF24(1-)

C12H11N*H(1+)*C32H12BF24(1-)

Conditions
ConditionsYield
In diethyl ether at 20℃; for 1h; Glovebox; Inert atmosphere;100%
2,2,6-trimethyl-4H-1,3-dioxin-4-one
5394-63-8

2,2,6-trimethyl-4H-1,3-dioxin-4-one

diphenylamine
122-39-4

diphenylamine

N,N-diphenylacetoacetamide
2540-31-0

N,N-diphenylacetoacetamide

Conditions
ConditionsYield
In toluene at 20℃; for 12.25h; Reflux;100%
1-(2,6-diisopropylphenyl)-3,3,5,5-tetramethylpyrrolidin-2-ylidene

1-(2,6-diisopropylphenyl)-3,3,5,5-tetramethylpyrrolidin-2-ylidene

diphenylamine
122-39-4

diphenylamine

C32H42N2

C32H42N2

Conditions
ConditionsYield
In pentane at 20℃; for 0.5h; Inert atmosphere; Glovebox; Schlenk technique;100%
(5R,6S,9R)-2-(2,6-diisopropylphenyl)-6-isopropyl-3,3,9-trimethyl-2-azaspiro[4.5]decan-1-ylidene
869085-78-9

(5R,6S,9R)-2-(2,6-diisopropylphenyl)-6-isopropyl-3,3,9-trimethyl-2-azaspiro[4.5]decan-1-ylidene

diphenylamine
122-39-4

diphenylamine

C39H54N2

C39H54N2

Conditions
ConditionsYield
In pentane at 20℃; for 0.5h; Inert atmosphere; Glovebox;100%

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