cas 618-57-5, 2-PROPYL SUCCINIC ACID | Articles data ｜lookchem

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618-57-5

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Nitroalkanes and dimethyl maleate as source of 3-alkyl succinic anhydrides and (E)-3-alkylidene succinic anhydrides
Nitroalkanes react with dimethyl maleate giving a tandem Michael addition/elimination of nitrous acid. The obtained (E)-2-alkylidene dimethyl succinates are: (i) reduced to the corresponding 2-alkyl dimethyl succinates which after hydrolysis produce 1,4-dicarboxylic acids that are prone to convert into the corresponding 3-alkyl succinic anhydrides or (ii) hydrolysed to (E)-2-alkylidene-succinic acids that are easily cyclised to (E)-3-alkylidene succinic anhydrides.
Ballini, Roberto,Bosica, Giovanna,Fiorini, Dennis,Righi, Paolo
p. 681 - 685
(2007/10/03)

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Chemical Properties

Melting Point: 100.5 °C
Boiling Point: 265.8±13.0 °C(Predicted)
Density: 1 +-.0.06 g/cm3(Predicted)
PKA: 4.56±0.19(Predicted)
PSA: 74.60000
LogP: 0.96200

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