- Access to Stable Quaternary Phosphiranium Salts by P-Alkylation and P-Arylation of Phosphiranes
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We report the preparation of phosphiranium salts by quaternarization of phosphiranes, a class of sensitive, highly strained, and poorly nucleophilic cyclic phosphines. High-yielding introduction of a varied set of alkyl groups including methylene ester ar
- Alayrac, Carole,Botella, Clément,Comesse, Sébastien,Dalla, Vincent,Gasnot, Julien,Gaumont, Annie-Claude,Lakhdar, Sami,Taillier, Catherine
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- Taming the Reactivity of Phosphiranium Salts: Site-Selective C-Centered Ring Opening for Direct Synthesis of Phosphinoethylamines
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Advances in the field of phosphorus chemistry are documented, by revealing the synthetic utility of previously underutilized quaternary phosphiranium salts (QPrS) as three-chain-atom electrophilic building blocks. Notably, control of their challenging C-centered electrophilicity is disclosed with an expedient synthesis of tertiary β-anilino phosphines as a proof-of-concept.
- Alayrac, Carole,Botella, Clément,Comesse, Sébastien,Dalla, Vincent,Gasnot, Julien,Gaumont, Annie-Claude,Lakhdar, Sami,Taillier, Catherine
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supporting information
p. 11769 - 11773
(2020/05/22)
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- HERBICIDAL COMPOUNDS
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The present invention relates to a compound of formula (I) wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11 and G are as defined herein; and wherein the compound of formula (I) is optionally present as an agrochemically acceptable salt thereof. These compounds are suitable for use as herbicides. The invention therefore also relates to a method of controlling weeds, especially grassy monocotyledonous weeds, in crops of useful plants, comprising applying a compound of formula (I), or a herbicidal composition comprising such a compound, to the plants or to the locus thereof.
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Page/Page column 82
(2016/05/24)
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- Synthesis of 1-Substituted-7-hydroxyquinolinium Salts
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The reaction of 7-acetoxyquinoline with trifluorosulfonate esters of primary alcohols in methylene chloride or acetonitrile, followed by acid hydrolysis, provides a general synthesis of 1-substituted-7-hydroxyquinolines, whose phenolate anions are fluorescent.
- Ranganathan, N.,Storey, B. T.
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p. 1069 - 1072
(2007/10/02)
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