61836-02-0

Basic information

• Product Name: 2-Trifluoromethanesulfonyloxyaceticacidethylester
• Synonyms: 2-Trifluoromethanesulfonyloxyaceticacidethylester;Ethoxycarbonylmethyl Trifluoromethanesulfonate
• CAS NO: 61836-02-0
• Molecular Formula: C₅H₇F₃O₅S
• Molecular Weight: 236.1662896
• Mol File: 61836-02-0.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-Trifluoromethanesulfonyloxyaceticacidethylester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Trifluoromethanesulfonyloxyaceticacidethylester(61836-02-0)
• EPA Substance Registry System: 2-Trifluoromethanesulfonyloxyaceticacidethylester(61836-02-0)

Safety Data

• Hazardous Substances Data: 61836-02-0(Hazardous Substances Data)

Upstream product

• 623-73-4 diazoacetic acid ethyl ester 
• 1493-13-6 trifluorormethanesulfonic acid 
• 623-50-7 ethyl 2-hydroxyacetate 
• 358-23-6 trifluoromethylsulfonic anhydride 

Downstream Products

• 63909-23-9 (1-Cyano-cyclohexyl)-dimethylamino-acetic acid ethyl ester 
• 63909-27-3 3-Cyano-2-dimethylamino-3-methyl-5-phenyl-pentanoic acid ethyl ester 
• 61836-18-8 Methylsulfanyl-((Z)-1-phenyl-pent-1-enyloxy)-acetic acid ethyl ester 
• 61836-19-9 Methylsulfanyl-(6-phenyl-cyclohex-1-enyloxy)-acetic acid ethyl ester 
• 95412-88-7 1-Ethoxycarbonylmethyl-1-methyl-2-phenylethynyl-1,2,3,6-tetrahydro-pyridinium; bromide 
• 84218-23-5 Trifluoro-methanesulfonate1-ethoxycarbonylmethyl-2-phenylethynyl-thiepanium; 
• 108277-81-2 Trifluoro-methanesulfonate1-ethoxycarbonylmethyl-2-phenylethynyl-thiochromanium; 
• 108277-93-6 Trifluoro-methanesulfonate2-ethoxycarbonylmethyl-1-phenylethynyl-isothiochromanium; 
• 108795-88-6 1-(carbethoxymethyl)-3,4-dicarbomethoxy-2,2-diphenyl-3-pyrroline 
• 108795-84-2 2-carbethoxy-3,4-dicarbomethoxy-1-methyl-5,5-diphenyl-3-pyrroline 
• 190278-32-1 3,10-Bis-benzyloxy-13-(4-benzyloxy-3-methoxy-phenyl)-2,11-dimethoxy-5-oxa-6b-aza-dibenzo[a,i]fluoren-6-one 

Relevant articles and documents

Access to Stable Quaternary Phosphiranium Salts by P-Alkylation and P-Arylation of Phosphiranes

We report the preparation of phosphiranium salts by quaternarization of phosphiranes, a class of sensitive, highly strained, and poorly nucleophilic cyclic phosphines. High-yielding introduction of a varied set of alkyl groups including methylene ester ar

Taming the Reactivity of Phosphiranium Salts: Site-Selective C-Centered Ring Opening for Direct Synthesis of Phosphinoethylamines

Advances in the field of phosphorus chemistry are documented, by revealing the synthetic utility of previously underutilized quaternary phosphiranium salts (QPrS) as three-chain-atom electrophilic building blocks. Notably, control of their challenging C-centered electrophilicity is disclosed with an expedient synthesis of tertiary β-anilino phosphines as a proof-of-concept.

HERBICIDAL COMPOUNDS

The present invention relates to a compound of formula (I) wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11 and G are as defined herein; and wherein the compound of formula (I) is optionally present as an agrochemically acceptable salt thereof. These compounds are suitable for use as herbicides. The invention therefore also relates to a method of controlling weeds, especially grassy monocotyledonous weeds, in crops of useful plants, comprising applying a compound of formula (I), or a herbicidal composition comprising such a compound, to the plants or to the locus thereof.

Synthesis of 1-Substituted-7-hydroxyquinolinium Salts

The reaction of 7-acetoxyquinoline with trifluorosulfonate esters of primary alcohols in methylene chloride or acetonitrile, followed by acid hydrolysis, provides a general synthesis of 1-substituted-7-hydroxyquinolines, whose phenolate anions are fluorescent.