62361-02-8Relevant articles and documents
Process for producing fluorinated vinyl ether
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Page 6, (2008/06/13)
There is provided a process for producing a fluorinated vinyl ether from a fluorinated acid fluoride compound having an ester group as a precursor of a carboxylic acid group, or a SO2F group as a precursor of a sulfonic acid group, in high yield by simple operations. Said process is a production process comprising pyrolyzing a carboxylic acid potassium salt with a specific structure represented by the following formula in the absence of a solvent and/or while maintaining the salt in the solid state: wherein X is —CO2R or —SO2F, and R is an alkyl group.
Synthesis of perfluorinated vinyl ethers having ester group
Yamabe, Masaaki,Munekata, Seiji,Kaneko, Isamu,Ukihashi, Hiroshi
, p. 65 - 68 (2007/10/03)
A new efficient and convenient synthetic process of perfluorinated vinyl ethers containing an ester group was developed by pyrolysis in the presence of α-trifluoromethyl moiety without loss of -COF functional group followed by alcoholysis in high yield.