62614-70-4

Basic information

• Product Name: CIS-6-CHLORO-2-HEXENE
• Synonyms: CIS-4-HEXEN-1-YL CHLORIDE;CIS-6-CHLORO-2-HEXENE;Chlorohexene;cis-6-chloro-2-hexene90+%
• CAS NO: 62614-70-4
• Molecular Formula: C₆H₁₁Cl
• Molecular Weight: 118.6
• Mol File: 62614-70-4.mol

Chemical Properties

• Boiling Point: 132 °C
• Appearance: /
• Density: 0.92
• Refractive Index: 1.4420-1.4450
• CAS DataBase Reference: CIS-6-CHLORO-2-HEXENE(CAS DataBase Reference)
• NIST Chemistry Reference: CIS-6-CHLORO-2-HEXENE(62614-70-4)
• EPA Substance Registry System: CIS-6-CHLORO-2-HEXENE(62614-70-4)

Safety Data

• RIDADR: 1993
• Hazardous Substances Data: 62614-70-4(Hazardous Substances Data)

Usage

Uses

Used in Pharmaceutical Industry:
CIS-6-CHLORO-2-HEXENE is used as a chemical intermediate for the synthesis of various pharmaceuticals. Its unique structure allows for the creation of a wide range of medicinal compounds, contributing to the development of new drugs and therapies.
Used in Agrochemical Industry:
In the agrochemical industry, CIS-6-CHLORO-2-HEXENE serves as a key intermediate in the production of various agrochemicals. Its role in synthesizing active ingredients for pesticides and herbicides helps improve crop protection and yield.
Used in Specialty Chemicals Production:
CIS-6-CHLORO-2-HEXENE is utilized as an intermediate in the synthesis of specialty chemicals, which are used in a variety of applications, including fragrances, dyes, and other industrial chemicals.
Used in Polymer Production:
CIS-6-CHLORO-2-HEXENE is also used in the production of polymers, contributing to the development of new materials with specific properties for various applications in industries such as plastics, textiles, and coatings.
Used as a Solvent in Industrial Applications:
CIS-6-CHLORO-2-HEXENE functions as a solvent in various industrial processes, aiding in the dissolution and reaction of other chemicals, which is essential for numerous manufacturing operations.
However, it is important to note that CIS-6-CHLORO-2-HEXENE is considered toxic if inhaled, causing irritation to the respiratory system, and is harmful if swallowed or comes into contact with the skin, causing irritation and burns. Therefore, proper safety precautions must be followed when handling this chemical.

InChI:InChI=1/C6H11Cl/c1-2-3-4-5-6-7/h2-3H,4-6H2,1H3/b3-2-

Upstream product

• 629-11-8 1,6-hexanediol 
• 928-89-2 6-chlorohexene 
• 6126-50-7 hex-4-en-1-ol 
• 928-93-8 4-hexyn-1-ol 
• 14267-92-6 1-chloro-4-pentyne 
• 28077-73-8 6-chlorohex-2-yne 
• 928-91-6 (Z)-4-hexenol 
• 821-41-0 5-Hexen-1-ol 
• 928-92-7 (E)-hex-4-en-1-ol 

Downstream Products

• 70681-89-9 ((E)-3-Hex-4-enyl)-cyclohex-2-enol 
• 2931-10-4 2-ethylcyclopent-2-en-1-one 
• 1121-18-2 2-methyl-2-cyclohexen-1-one 
• 105-21-5 4-propylbutanolide 
• 70681-91-3 3-<(E)-4-hexenyl>-2-cyclohexen-1-one 

Relevant articles and documents

Site-selective catalytic deaminative alkylation of unactivated olefins

A catalytic deaminative alkylation of unactivated olefins is described. The protocol is characterized by its mild conditions, wide scope - including the use of ethylene as substrate -, and exquisite site-selectivity pattern for both a-olefins and internal olefins, thus unlocking a new catalytic platform to forge sp3-sp3 linkages, even in the context of late-stage functionalization.

Benign catalysis with iron: Unique selectivity in catalytic isomerization reactions of olefins

The use of noble metal catalysts in homogeneous catalysis has been well established. Due to their price and limited availability, there is growing interest in the substitution of such precious metal complexes with readily available and bio-relevant catalysts. In particular, iron is a "rising star" in catalysis. Herein, we present a general and selective iron-catalyzed monoisomerization of olefins, which allows for the selective generation of 2-olefins. Typically, common metal complexes give mixtures of various internal olefins. Both bulk-scale terminal olefins and functionalized terminal olefins give the corresponding products under mild conditions in good to excellent yields. The proposed reaction mechanism was elucidated by in situ NMR studies and supported by DFT calculations and extended X-ray absorption fine structure (EXAFS) measurements.

Diastereoselective cycloisomerizations of enediynes via palladium catalysis

Considerations of atom economy drive a search for reactions that are simple additions which, performed intramolecularly, are cycloisomerizations. Exposure of acyclic enediynes to a catalyst generated by mixing a Pd(0) complex with acetic acid normally in

Medicaments, vicinal dihydroxyalkylxanthines contained therein, processes for the preparation of these xanthine compounds and intermediate products suitable for these

Compounds of the formula STR1 wherein one of the radicals R1, R2 or R3 denotes a straight-chain alkyl group having 4 to 8 C atoms and two vicinal hydroxyl groups in the ω,ω-1 or ω-1,ω-2 positions and the two other radicals represent straight-chain or branched alkyl groups having up to 12 C atoms in the position of R1 and R3 and up to 4 C atoms in the position of R2, the total of C atoms in these two alkyl substituents being a maximum of 14, are prepared by oxidation of the corresponding alkenylxanthines and by alkylation with compounds which introduce the dihydroxyalkyl radical or a precursor thereof. The dihydroxyalkyldialkylxanthines are suitable for the treatment of obstructive respiratory tract diseases.

Photochemistry of N-Alk-4-enyl and N-Alk-5-enyl-phthalimides: Two Different Types of Cyclization Reaction

Photochemical reactions of N-alk-4- and -5-enylphthalimides (1a-e) have been investigated.In the photolyses of acetonitrile solutions of (1a-e), intramolecular cyclization reactions accompanying C(=O)-N bond cleavage to give (2a-e) were generally predominant, together with intramolecular hydrogen abstraction in some cases.Photolyses of cis- and trans-N-hex-4-enylphthalimides in acetonitrile solution showed stereospecific cyclization reactions; irridiation of cis-(1e) gave cis-(2e) and that of trans-(1e) gave trans-(2e) selectively with low conversion.In methanol (1d), which has a vinyl ether moiety, gave different types of cyclization product: namely, (8a) and (9a), methanol-incorporated products probably resulting from an intramolecular electron transfer process.