Zirconocene-Initiated Intramolecular Hydride Transfer in N -Isoalkyl-Substituted Propargylamines
The unusual transformation of N -isoalkyl-substituted propargylamines into alkenylamines under the action of Cp 2 ZrCl 2 and organoaluminum compounds (Me 3 Al, EtAlCl 2) has been observed. The proposed mechanism, involving the N -isoalkyl-substituted propargylamine undergoing zirconocene-initiated intramolecular hydride transfer was supported by B3LYP/6-31G(d)/LanL2DZ calculations.
Ramazanov, Ilfir R.,Kadikova, Rita N.,Saitova, Zukhra R.,Dzhemilev, Usein M.
p. 1191 - 1194
(2018/03/21)
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