cas 6341-54-4, 1-Naphthaleneglycolic acid | Articles data ｜lookchem

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6341-54-4

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Normal Pressure Double Carbonylation of Aryl Halides Using Cobalt(II) Chloride in the Presence of either Sodium Sulfide or Sodium Borohydride
Tetracarbonylcobaltate ion generated by a treatment of cobalt(II) chloride with either sodium sulfide or sodium borohydride under a normal pressure of carbon monoxide was capable of catalyzing carbonylation of aryl halides in the presence of calcium hydroxide and methyl iodide to give arylglyoxylic acids in good selectivity.
Itoh, Kenji,Miura, Masahiro,Nomura, Masakatsu
p. 4151 - 4152
(2007/10/02)

ONE-STEP SYNTHESIS OF α-HYDROXY ACIDS VIA REDUCTIVE DOUBLE CARBONYLATION OF ORGANIC HALIDES
Palladium-catalyzed carbonylation of organic halides with water in the presence of calcium hydroxide or lithium hydroxide in primary or secondary alcoholic solvents afforded α-hydroxy acids.
Kobayashi, Toshi-aki,Sakakura, Toshiyasu,Tanaka, Masato
p. 2721 - 2722
(2007/10/02)

Cobalt-Catalyzed Normal Pressure Carbonylation of Aryl Halides. Notable Solvent Effects on the Ratio of Mono- to Double-Carbonylation
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Miura, Masahiro,Akase, Fumiaki,Nomura, Masakatsu
p. 2623 - 2625
(2007/10/02)

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Chemical Properties

Melting Point: 80 °C
Boiling Point: 428.9°C at 760 mmHg
Flash Point:227.3°C
Density: 1.354g/cm³
Vapor Pressure: 4.04E-08mmHg at 25°C
PKA: 3.42±0.30(Predicted)
PSA: 57.53000
LogP: 1.95780

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