634164-29-7

Basic information

• Product Name: Furo[3,2-b]pyridine,2,3-dihydro-3-methyl-(9CI)
• Synonyms: Furo[3,2-b]pyridine,2,3-dihydro-3-methyl-(9CI);2,3-Dihydro-3-methylfuro[3,2-b]pyridine
• CAS NO: 634164-29-7
• Molecular Formula: C8H9NO
• Molecular Weight: 135.16316
• Product Categories: PYRIDINE
• Mol File: 634164-29-7.mol

Chemical Properties

• Boiling Point: 203.5±19.0 °C(Predicted)
• Appearance: /
• Density: 1.100±0.06 g/cm3(Predicted)
• PKA: 6.06±0.40(Predicted)
• CAS DataBase Reference: Furo[3,2-b]pyridine,2,3-dihydro-3-methyl-(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Furo[3,2-b]pyridine,2,3-dihydro-3-methyl-(9CI)(634164-29-7)
• EPA Substance Registry System: Furo[3,2-b]pyridine,2,3-dihydro-3-methyl-(9CI)(634164-29-7)

Safety Data

• Hazardous Substances Data: 634164-29-7(Hazardous Substances Data)

Upstream product

• 109-00-2 3-HYDROXYPYRIDINE 
• 18343-04-9 3-(allyloxy)-pyridine 
• 6602-32-0 2-bromo-pyridin-3-ol 
• 40263-57-8 2-iodo-3-hydroxypyridine 
• 123552-77-2 3-(allyloxy)-2-bromopyridine 
• 140-88-5 ethyl acrylate 
• 107-13-1 acrylonitrile 

Relevant articles and documents

Hydropyridylation of Olefins by Intramolecular Minisci Reaction

An unprecedented cheap, mild and easy methodology for an intramolecular Minisci reaction based on a hydrogen atom transfer (HAT) initiated hydrofunctionalization of olefins was developed. The method is suitable for the construction of unusual dihydropyrano-pyridine and 1,2,3,4-tetrahydronaphthiridine structures and, unlike most similar reactions, does not require exclusion of air from the reaction medium.

A mild catalytic system for radical conjugate addition of nitrogen heterocycles

The direct addition of pyridine and diazine units to electron-poor alkenes has been achieved via a redox radical mechanism that is enabled by limiting the effective concentration of the hydrogen-atom source. The described method is tolerant of acidic functional groups and is generally applicable to the union of a wide range of Michael acceptors and 6-membered heterocyclic halides.

Diastereoselective intramolecular SmI2-H2O-amine mediated couplings

The effectiveness of SmI2-H2O-amine mixture for intramolecular couplings was discussed. Diastereoselectivities in the coupling of O-cyclohexanyliodophenol derivatives were provided into heterocycles. The amount of coupled product improved significantly as SmI2, the substrate and amine were premixed followed by a gradual addition of water.

THE REACTIONS OF ALLYL o-BROMOARYL ETHERS, N-ALLYL o-BROMOACETANILIDE, AND RELATED COMPOUNDS WITH TRIBUTYLTIN HYDRIDE IN THE PRESENCE OF ACTIVATED OLEFINS

o-Bromophenyl allyl ether, N-allyl o-bromoacetanilide, and related compounds reacted with tributyltin hydride in the presence of activated olefins to give 2,3-dihydrobenzofuran, 2,3-dihydroindole, and analogous derivatives in modest yields respectively vi