- Synthesis of 7,8-Dihydroxy-5-hydroxymethyl-2-phenyl-chroman-4-one; the Aglycon of Actinoflavoside
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The first synthesis of 7,8-dihydroxy-5-hydroxymethyl-2-phenyl-chroman-4- one, the aglycon part of a new-type glucoside, actinoflavoside, was accomplished. The regioselective oxidation of the methyl group at the 5-position in 7,8-dihydroxy-5-methyl-2-phenyl-chroman-4-one derived from 3,4,5-trimethoxytoluene was performed by use of ammonium cerium(VI) nitrate (CAN).
- Suzuki, Katsuhiko,Tsuruga, Takeshi,Hiranuma, Kyoko,Yamaura, Masanori
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p. 116 - 118
(2007/10/03)
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