cas 658-08-2, (3-FLUORO-PHENYL)-OXO-ACETONITRILE | Articles data ｜lookchem

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658-08-2

Articles about 658-08-2Total 2 be found

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A Cyanide-Free Synthesis of Acylcyanides through Ru-Catalyzed C(sp3)-H-Oxidation of Benzylic Nitriles
A practical method for generation of acylcyanides devoid of any external cyanide sources is presented that relies on a mild Ru-catalyzed selective C?H-oxidation of benzylic nitriles. The starting materials are smoothly generated through condensation of the corresponding carboxylic acid amides using silanes. The obtained acylcyanides can be employed in a plethora of transformation as exemplified to some larger extend in the sequence of C?H-oxidation-Tischenko-rearrangement for the generation of structurally diverse benzoyloxycyanohydrines.
Eisele, Pascal,Bauder, Michael,Hsu, Shih-Fan,Plietker, Bernd
p. 689 - 691
(2019/05/07)

Tin Chloride-Catalyzed Preparation of Aroyl Cyanides from Aroyl Chlorides and Cyanotrimethylsilane
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Olah, George A.,Arvanaghi, Massoud,Prakash, G. K. Surya
p. 636 - 637
(2007/10/02)

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Chemical Properties

Boiling Point: 72-74 °C(Press: 0.25 Torr)
Density: 1.257±0.06 g/cm3(Predicted)
PSA: 40.86000
LogP: 1.53198

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