cas 669713-98-8, 4-(2'-N-BOC-PYRROLE)BENZOIC ACID | Articles data ｜lookchem

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669713-98-8

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Sensitized photografting of diazonium salts by visible light.
Visible irradiation of a gold surface dipped into a solution of diversely substituted aryldiazonium salts in the presence of a photosensitizer (Ru(bipy)32+ or eosinY) leads to a modification of the surface by attached aryl groups. A grafted nanometer thick polyphenylene film is obtained. The reaction is extended to a polyvinylchloride (PVC) surface. The mechanism proposed for the formation of this film involves the formation of an aryl radical that reacts with the surface and then with the first grafted aryl group. The film is characterized by infrared reflection absorption spectroscopy (IRRAS), X-ray photoelectron spectroscopy (XPS), water contact angles, and ellipsometry.
Bouriga, Meriem,Chehimi, Mohamed M.,Combellas, Catherine,Decorse, Philippe,Kanoufi, Frederic,Deronzier, Alain,Pinson, Jean
p. 90 - 97
(2013/03/14)

Self-sorting self-complementary assemblies of π-conjugated acyclic anion receptors
Pyrrole-based π-conjugated anion-responsive molecules bearing an anionic moiety form self-complementary dimers, which exhibit self-sorting behaviours depending on the substituted positions of anionic sites.
Maeda, Hiromitsu,Kinoshita, Kota,Naritani, Kazumasa,Bando, Yuya
supporting information; experimental part
p. 8241 - 8243
(2011/09/16)

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Chemical Properties

Boiling Point: 454.3°C at 760 mmHg
Flash Point:228.5°C
Density: 1.17g/cm³
Vapor Pressure: 4.83E-09mmHg at 25°C
Refractive Index: 1.558
PKA: 4.21±0.10(Predicted)
PSA: 68.53000
LogP: 3.63650

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