67116-33-0

Basic information

• Product Name: 2-BROMO-3-NITRONAPHTHALENE
• Synonyms: 2-BROMO-3-NITRONAPHTHALENE;Naphthalene, 2-broMo-3-nitro-
• CAS NO: 67116-33-0
• Molecular Formula: C₁₀H₆BrNO₂
• Molecular Weight: 252.06
• Mol File: 67116-33-0.mol

Chemical Properties

• Melting Point: 82-83 °C
• Boiling Point: 338.13 °C at 760 mmHg
• Flash Point: 158.295 °C
• Appearance: /
• Density: 1.663 g/cm³
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.696
• CAS DataBase Reference: 2-BROMO-3-NITRONAPHTHALENE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-BROMO-3-NITRONAPHTHALENE(67116-33-0)
• EPA Substance Registry System: 2-BROMO-3-NITRONAPHTHALENE(67116-33-0)

Safety Data

• Hazard Codes: Xi
• HazardClass: IRRITANT
• Hazardous Substances Data: 67116-33-0(Hazardous Substances Data)

Usage

Uses

Used in Organic Synthesis:
2-Bromo-3-Nitronaphthalene is used as an intermediate in the synthesis of various organic compounds. Its unique structure, featuring a bromine atom and a nitro group, makes it a valuable building block for the creation of complex molecules in the field of organic chemistry.
Used in Pharmaceutical Industry:
2-Bromo-3-Nitronaphthalene is used as a key component in the development of pharmaceuticals. Its chemical properties allow it to be incorporated into drug molecules, potentially leading to the discovery of new therapeutic agents with novel mechanisms of action.
Used in Chemical Research:
2-Bromo-3-Nitronaphthalene is used as a research tool in academic and industrial laboratories. Its reactivity and structural features make it an interesting subject for studies in organic chemistry, potentially leading to new insights and advancements in the field.
Used in Material Science:
2-Bromo-3-Nitronaphthalene is used in the development of new materials with specific properties. Its incorporation into polymers or other materials can result in materials with unique characteristics, such as improved stability, enhanced reactivity, or novel optical properties.

InChI:InChI=1/C10H6BrNO2/c11-9-5-7-3-1-2-4-8(7)6-10(9)12(13)14/h1-6H

Upstream product

• 90766-99-7 2-bromo-3-nitro-[1]naphthylamine 
• 54245-33-9 3-bromonaphthalen-2-amine 
• 81615-01-2 6-Brom-7-nitro-tetralin 
• 856210-98-5 3-bromo-2-nitro-[1]naphthylamine 
• 84605-00-5 10-bromo-1,2,3,4,5,6,7,8,13,13,14,14-dodecachloro-1,4,4a,4b,5,8,8a,12b-octahydro-11-nitro-1,4-5,8-dimethanotriphenylene 
• 13115-28-1 3-nitronaphthalen-2-amine 
• 7726-95-6 bromine 
• 92025-23-5 N-(2-bromo-3-nitro-[1]naphthyl)-acetamide 
• 855930-11-9 N-(3-bromo-[1]naphthyl)-acetamide 
• 860746-85-6 N-(3-bromo-2-nitro-[1]naphthyl)-acetamide 

Downstream Products

• 81615-04-5 2-Nitro-3-phenoxynaphthalin 
• 54245-33-9 3-bromonaphthalen-2-amine 
• 102153-71-9 2-iodo-3-nitronaphthalene 
• 116632-14-5 2-amino-3-iodonaphthalene 
• 81615-05-6 3-Phenoxy-2-naphthylamin 
• 81615-06-7 N-(3-Phenoxy-2-naphthyl)-methansulfonamid 
• 242-50-2 6H-dibenzo[b,h] carbazole 
• 243-28-7 2,3-benzocarbazole 
• 92795-23-8 3-phenyl-2-nitronapthalene 

Relevant articles and documents

Relative binding affinity of carboxylate and its isosteres: Nitro, phosphate, phosphonate, sulfonate, and δ-lactone

Using the mono and ditopic receptors 1 and 2 (N-n-butyl-N′-p-tolylurea and 4,8-bis[((n-butylamino)carbonyl)amino]dibenz[b, i]acridan), the relative binding affinities of the title functional groups were determined to be ArOPO32- ≥ ArPO32- > ArCOO- ≥ ArP(OH)O2- > ArOP(OH)O2- > ArSO3- > δ-lactone > ArNO2. No evidence of hydrogen bonding of nitrobenzene to 1 was detected in either CDCl3 or DMSO-d6, but in CCl4, Kassoc = 180 M-1. Ditopic receptor 2 was designed as a receptor for meta-disubstituted aromatic substrates and binds some (isophthalate and 1,3-C6H4(P(OH)O2-)2) with high affinity (Kassoc > 104 M-1) in DMSO-d6. In contrast, the isosteric m-dinitrobenzene is not bound by 2 in that solvent, which further illustrates the relatively poor hydrogen bonding ability of nitro groups.