676593-23-0

Basic information

• Product Name: 1,3,2-Dioxaborinane, 2-(4-ethenylphenyl)-5,5-dimethyl-
• CAS NO: 676593-23-0
• Molecular Formula: C13H17BO2
• Molecular Weight: 216.088
• Mol File: 676593-23-0.mol

Chemical Properties

• CAS DataBase Reference: 1,3,2-Dioxaborinane, 2-(4-ethenylphenyl)-5,5-dimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3,2-Dioxaborinane, 2-(4-ethenylphenyl)-5,5-dimethyl-(676593-23-0)
• EPA Substance Registry System: 1,3,2-Dioxaborinane, 2-(4-ethenylphenyl)-5,5-dimethyl-(676593-23-0)

Safety Data

• Hazardous Substances Data: 676593-23-0(Hazardous Substances Data)

Usage

Chemical class

Dioxaborinane compounds
It belongs to a class of compounds that contain a boron atom bonded to two oxygen atoms and a five-membered ring.

Structure

Dioxaborinane ring with a phenyl group and two methyl groups
The compound has a dioxaborinane ring structure, which includes a phenyl group with an ethenyl substituent and two methyl groups attached to the boron atom.

Reactivity

Versatile in chemical reactions
Due to its structure, the compound is reactive and can participate in various chemical reactions, making it a useful building block in organic synthesis.

Applications

Organic synthesis, pharmaceuticals, and material science
It is commonly used in the creation of organic compounds and complex molecules, particularly in the fields of pharmaceuticals and material science.

Precursor potential

Development of new materials
The compound has the potential to be used as a precursor in the development of new materials with unique properties and functions.

Molecular weight

Approximately 169.03 g/mol
The molecular weight is an estimate of the mass of one mole of the compound, which can be useful for determining the concentration of a solution or the amount of compound needed for a specific reaction.

Stability

Stable under normal conditions
The compound is generally stable under normal laboratory conditions, making it suitable for use in various chemical reactions and applications.

Solubility

Soluble in organic solvents
It is soluble in common organic solvents, such as dichloromethane, tetrahydrofuran, and dimethyl sulfoxide, which facilitates its use in chemical reactions.

Safety precautions

Handle with care due to potential hazards
As with any chemical compound, it is essential to follow proper safety protocols when handling 1,3,2-Dioxaborinane, 2-(4-ethenylphenyl)-5,5-dimethyl-, including wearing appropriate personal protective equipment and working in a well-ventilated area.

Upstream product

• 2156-04-9 4-Vinylphenylboronic acid 
• 126-30-7 2,2-Dimethyl-1,3-propanediol 
• 2039-82-9 1-bromo-4-ethenyl-benzene 

Downstream Products

• 1076-96-6 methyl 4-vinylbenzoate 
• 69135-05-3 2-(4-vinylphenyl)pyridine 
• 1590366-87-2 2-phenyl-6-(4-vinylphenyl)pyridine 
• 4714-11-8 p-Vinyl α,β,β-trifluorostyrene 
• 1075-49-6 4-ethenylbenzoic acid 

Relevant articles and documents

Ruthenium-Catalyzed Carbonylative Coupling of Anilines with Organoboranes by the Cleavage of Neutral Aryl C-N Bond

Herein, we report the first ruthenium-catalyzed Suzuki-type carbonylative reaction of electronically neutral anilines via C(aryl)-N bond cleavage. Without any ligand and base, diaryl ketones can be obtained in moderate to high yields by using Ru3/su

Ruthenium-Catalyzed Reductive Arylation of N-(2-Pyridinyl)amides with Isopropanol and Arylboronate Esters

A new three-component reductive arylation of amides with stable reactants (iPrOH and arylboronate esters), making use of a 2-pyridinyl (Py) directing group, is described. The N-Py-amide substrates are readily prepared from carboxylic acids and PyNH2, and the resulting N-Py-1-arylalkanamine reaction products are easily transformed into the corresponding chlorides by substitution of the HN-Py group with HCl. The 1-aryl-1-chloroalkane products allow substitution and cross-coupling reactions. Therefore, a general protocol for the transformation of carboxylic acids into a variety of functionalities is obtained. The Py-NH2 by-product can be recycled.

Selective Monoarylation of Aromatic Ketones and Esters via Cleavage of Aromatic Carbon-Heteroatom Bonds by Trialkylphosphine Ruthenium Catalysts

We report here the ruthenium-catalyzed selective monoarylation of aromatic ketones bearing two ortho carbon-heteroatom (O or N) bonds. Under the newly developed catalyst system consisting of RuHCl(CO)(PiPr3)2, CsF, and sty

PH-Responsive N-heterocyclic carbene copper(i) complexes: Syntheses and recoverable applications in the carboxylation of arylboronic esters and benzoxazole with carbon dioxide

A pH-controlled monophasic/biphasic switchable system has been developed as a green and novel strategy for homogeneous catalyst recycling, which has been successfully applied to the Cu-NHC-catalyzed carboxylation of organoboronic esters and benzoxazole with carbon dioxide. Additionally, the present strategy could also be extended to the Ag-NHC-catalyzed carboxylation of terminal alkyne. The tertiary amine-functionalized catalysts could be used for at least four times with a slight loss of activity.

Copper(I)-catalyzed carboxylation of aryl- and alkenylboronic esters

(Chemical Equation Presented) The copper(I)-catalyzed carboxylation reaction of aryl- and alkenylboronic esters proceeded smoothly under CO 2 to give the corresponding carboxylic acid in good yield. This reaction showed wide generality with higher functional group tolerance compared to the corresponding Rh(I)-catalyzed reaction.

Carboxylation of organoboronic esters catalyzed by N-heterocyclic carbene copper(I) complexes

Copper complexes with a CO2 fixation: Copper(I) complexes serve as excellent catalysts for the carboxylation of aryl- and alkenylboronic esters with CO2, affording a variety of functionalized carboxylic acid derivatives (see scheme). Important active intermediates such as the copper(I) aryl and carboxylate complexes, [(IPr)CuR] and [(IPr)CuOCOR] (R = 4-MeOC 6H4, IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2- ylidene), are isolated and structurally characterized. (Chemical Equation Presented).

Ruthenium-catalyzed carbon-carbon bond formation via the cleavage of an unreactive aryl carbon-nitrogen bond in aniline derivatives with organoboronates

The RuH2(CO)(PPh3)3-catalyzed reaction of 2-amino-6-methylacetophenone with phenylboronic acid 2,2-dimethyl-1,3-propanediol ester in refluxing toluene gave the corresponding phenylation product in 83% yield via aryl carbon