677313-37-0Relevant articles and documents
Synthesis of Chiral Cyclohexenones from α-Campholenic, Fencholenic, and β-Campholenic Derivatives
Anhalt, Katrin,Sprung, Ines,Schulze, Klaus
, p. 1593 - 1606 (2007/10/03)
Optically active dimethylcyclohexenones, potential building blocks for enantioselective syntheses of various naturally active substances, were prepared. These compounds were obtained by oxidation with KMnO 4/Pb(OAc)4 or ozonolysis of the corresponding cyclopentenic precursors, followed by aldol condensation. During the course of the preparation intermediate diols and chiral polyfunctional carbonyl derivatives were separated and identified analytically.