cas 690-92-6, CIS-2,2-DIMETHYL-3-HEXENE | Articles data ｜lookchem

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690-92-6

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A Novel Stereoselective Route to cis-Olefins via Addition of Vinyl Cuprates to αβ-Unsaturated Sulphones and Subsequent Desulphonylation
Dialkenylcuprates, generated by addition of dialkylcuprates to acetylene, react with αβ-unsaturated sulphones to give cis-γδ-unsaturated sulphones which can be easily desulphonylated with retention of the double-bond configuration.
Chirico, Gioacchino De,Fiandanese, Vito,Marchese, Giuseppe,Naso, Francesco,Sciacovelli, Oronzo
p. 523 - 524
(1981)
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Olefine aus β-Hydroxycarbonsaeuren - Synthese von isomerenreinem α- und β-Asaron
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Mulzer, Johann,Lammer, Ortrud
p. 629 - 630
(2007/10/02)

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Chemical Properties

Melting Point: -137.35°C
Boiling Point: 105.55°C
Flash Point:4°C(lit.)
Density: 0.7086
Refractive Index: 1.4090-1.4130
PSA: 0.00000
LogP: 2.99870

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