A Novel Stereoselective Route to cis-Olefins via Addition of Vinyl Cuprates to αβ-Unsaturated Sulphones and Subsequent Desulphonylation

DOI: 10.1039/C39810000523

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 523 - 524 (1981)

Update date:2022-08-30

Topics:

Authors:

Chirico, Gioacchino De

Fiandanese, Vito

Marchese, Giuseppe

Naso, Francesco

Sciacovelli, Oronzo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/C39810000523

Dialkenylcuprates, generated by addition of dialkylcuprates to acetylene, react with αβ-unsaturated sulphones to give cis-γδ-unsaturated sulphones which can be easily desulphonylated with retention of the double-bond configuration.

Full text of DOI:10.1039/C39810000523

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:CIS-2,2-DIMETHYL-3-HEXENE

Cas No:690-92-6

R&D Labs maybe for 690-92-6

Shandong Xinke Petrochemical Co., Ltd.

Contact:+86-546-7277016

Address:Gudao Industrial Park, Hekou District, Dongying, Shandong Province, China
SHANDONG CREDAGRI CHEMICAL CO., LTD.

Contact:+86-531-88872050

Address:ROOM 601A, BUILDING 2, SHUNTAI SQUARE, NO. 2000 SHUNHUA ROAD, HI-TECH DEVELOPMENT ZONE, JINAN, CHINA.
Tianjin Tensing Fine Chemical Research Develop Centre

Contact:86-022-23718576,13032267585

Address:2-2-201,13 Guiyuan road,Huayuan Industry district,Tianjin,china
Jiangsu Zenji Pharmaceuticals LTD

Contact:+86-025-83172562; +1-224-888-1133(USA)

Address:No.5 Xinmofan Road
SuZhou LaiTeou

Contact:+86-0512-88957371

Address:shanghai

Relevant to this article

Synthesis of benzimidazole derivatives using heterogeneous ZnO nanoparticles

Doi:10.1080/00397911.2010.522294
(2012)
Selective thermal oxidation of 2,3-dimethyl-5-(phenyldiazenyl)-1-vinyl-1H- pyrrole to the corresponding pyrrole-2-carbaldehyde: Stabilization of the pyrrole ring by phenylazo substituent

Doi:10.1134/S1070428009100248
(2009)
Carbene Formation and Transfer at a Dinickel Active Site

Doi:10.1021/acs.organomet.8b00261
(2018)
Many-electron oxidation of water as treated within the framework of a functional chemical model of the manganese cofactor of oxidase in photosystem II of natural photosynthesis

Doi:10.1134/S0036024407020239
(2007)
An oxorhenium(V) Schiff-base complex: Synthesis, structure, spectroscopic characterization, electrochemistry, and DFT calculations

Doi:10.1080/00958972.2013.777955
(2013)
An excellent dual recycling strategy for the hypervalent iodine/nitroxyl radical mediated selective oxidation of alcohols to aldehydes and ketones

Doi:10.1039/c2gc16632a
(2012)

Article Doi